On the quality and stability of preferentially oriented (100) Pt nanoparticles: An electrochemical insight
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http://hdl.handle.net/10045/72579
Títol: | On the quality and stability of preferentially oriented (100) Pt nanoparticles: An electrochemical insight |
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Autors: | Arán-Ais, Rosa M. | Solla-Gullón, José | Herrero, Enrique | Feliu, Juan M. |
Grups d'investigació o GITE: | Electroquímica de Superficies | Electroquímica Aplicada y Electrocatálisis |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Paraules clau: | Surface structure | Pt single crystal electrodes | Pt nanocubes | In situ characterization | Structural stability |
Àrees de coneixement: | Química Física |
Data de publicació: | 1-de gener-2018 |
Editor: | Elsevier |
Citació bibliogràfica: | Journal of Electroanalytical Chemistry. 2018, 808: 433-438. doi:10.1016/j.jelechem.2017.06.015 |
Resum: | Previous knowledge shed by single crystal electrochemistry path the way to obtain better catalysts aiming fuel cell purposes. In this sense, tailoring shape-controlled nanoparticles has been a strategy followed over the past years to optimize the activity, selectivity and stability of electrocatalytic surface sensitive reactions by maximizing the exposure of certain facets of the nanocatalyst. In the present paper, preferentially oriented (100) nanoparticles synthesized by different methodologies have been electrochemically characterized and compared. The voltammetric profile of these cubic nanoparticles has also been compared with different platinum single crystal stepped surfaces, showing a singular fitting to the characteristic response of Pt(510). Subtle changes on the surface structure of platinum nanocubes due to surface degradation upon storage time in aqueous solution are pointed out in this work. The characteristic fingerprints of platinum surfaces and CO oxidation profiles have demonstrated to be powerful surface probes for the in situ detection of these minor structural reorganizations. |
Patrocinadors: | This work has been supported by the Ministry of Economy and Competitiveness (MINECO) through the project CTQ2016-76221-P and Generalitat Valenciana (project PROMETEO II/2014/013). J.S.G. acknowledges financial support from VITC (Vicerrectorado de Investigación y Transferencia de Conocimiento) of the University of Alicante. |
URI: | http://hdl.handle.net/10045/72579 |
ISSN: | 1572-6657 (Print) | 1873-2569 (Online) |
DOI: | 10.1016/j.jelechem.2017.06.015 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Drets: | © 2017 Elsevier B.V. |
Revisió científica: | si |
Versió de l'editor: | http://dx.doi.org/10.1016/j.jelechem.2017.06.015 |
Apareix a la col·lecció: | INV - LEQA - Artículos de Revistas INV - EQSUP - Artículos de Revistas |
Arxius per aquest ítem:
Arxiu | Descripció | Tamany | Format | |
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2018_Aran-Ais_etal_JElectrChem_final.pdf | Versión final (acceso restringido) | 1,45 MB | Adobe PDF | Obrir Sol·licitar una còpia |
2018_Aran-Ais_etal_JElectrChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 1,39 MB | Adobe PDF | Obrir Vista prèvia |
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