Indium-mediated allylation of carbonyl compounds in deep eutectic solvents
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http://hdl.handle.net/10045/117366
| Títol: | Indium-mediated allylation of carbonyl compounds in deep eutectic solvents |
|---|---|
| Autors: | González-Gallardo, Nerea | Saavedra, Beatriz | Guillena, Gabriela | Ramón, Diego J. |
| Grups d'investigació o GITE: | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) | Alternative Methodologies In Chemistry (AMIC) |
| Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Paraules clau: | Allylation | Green chemistry | Indium | Solvent effects | Sustainability |
| Àrees de coneixement: | Química Orgánica |
| Data de publicació: | 25-d’agost-2021 |
| Editor: | John Wiley & Sons |
| Citació bibliogràfica: | Applied Organometallic Chemistry. 2021, 35(12): e6418. https://doi.org/10.1002/aoc.6418 |
| Resum: | This study describes, for the first time, the in situ generation of indium organometallic reagents in environmentally friendly deep eutectic solvents (DESs). The allylation process of different carbonyl compounds is achieved mediated by indium metal and using cheap allyl chloride derivatives. The unique DES properties allow to perform the reaction at room temperature and under air, obtaining yields ranging from 45% to 99%. It is possible to recycle the reaction medium for at least four consecutive cycles without much decrease of the observed results. Also, a linear correlation between the yield of the reaction and the density of the DESs is observed. |
| Patrocinadors: | This work was supported by the University of Alicante (VIGROB-316FI and VIGORB20-170) and the Spanish Ministerio de Economia, Industria y Competitividad (PGC2018-096616-B-100). NGG and BS thank Generalitat Valenciana (ACIF/2020/186 and ACIF/2017/211, respectively) for their fellowships. |
| URI: | http://hdl.handle.net/10045/117366 |
| ISSN: | 0268-2605 (Print) | 1099-0739 (Online) |
| DOI: | 10.1002/aoc.6418 |
| Idioma: | eng |
| Tipus: | info:eu-repo/semantics/article |
| Drets: | © 2021 The Authors. Applied Organometallic Chemistry published by John Wiley & Sons Ltd. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| Revisió científica: | si |
| Versió de l'editor: | https://doi.org/10.1002/aoc.6418 |
| Apareix a la col·lecció: | INV - AMIC - Artículos de Revistas INV - CESO - Artículos de Revistas |
Arxius per aquest ítem:
| Arxiu | Descripció | Tamany | Format | |
|---|---|---|---|---|
 Gonzalez-Gallardo_etal_2021_ApplOrganometChem.pdf | 2,58 MB | Adobe PDF | Obrir Vista prèvia | |
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