Switchable Catalysts for Chemical CO2 Recycling: A Step Forward in the Methanation and Reverse Water–Gas Shift Reactions
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http://hdl.handle.net/10045/105407
Títol: | Switchable Catalysts for Chemical CO2 Recycling: A Step Forward in the Methanation and Reverse Water–Gas Shift Reactions |
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Autors: | Le Saché, Estelle | Pastor Pérez, Laura | Haycock, Bradley J. | Villora-Picó, Juan José | Sepúlveda-Escribano, Antonio | Ramírez Reina, Tomás |
Grups d'investigació o GITE: | Materiales Avanzados |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Paraules clau: | Switchable catalysts | CO2 recycling | RWGS | Methanation | RuNi catalyst |
Àrees de coneixement: | Química Inorgánica |
Data de publicació: | 6-de març-2020 |
Editor: | American Chemical Society |
Citació bibliogràfica: | ACS Sustainable Chemistry & Engineering. 2020, 8(11): 4614-4622. doi:10.1021/acssuschemeng.0c00551 |
Resum: | Advanced catalytic technologies are crucial to enable the transition toward a low-carbon industry with minimized CO2 emissions. This paper showcases the application of highly effective Ru-promoted Ni-based catalysts for gas-phase CO2 upgrading: CO2 methanation and reverse water–gas shift. The addition of small amounts of Ru results in a remarkable enhancement of CO2 conversion and selectivity. The bimetallic Ru-Ni catalyst displays greater metallic dispersion, tuned electronic properties and outstanding stability for long-term runs, a mandatory requisite for its implementation in actual CO2 conversion units. The singularity of our advanced catalyst lays on its capacity to work effectively for both the CO2 methanation and the reverse water–gas shift, allowing end-product flexibility by adjusting the reactor temperature. Such versatility opens a big range of possibilities to adapt this technology in heavy carbon industries whose net CO2 emissions represent a big share in the global greenhouse gases emissions. |
Patrocinadors: | Financial support for this work was provided by the Department of Chemical and Process Engineering at the University of Surrey and the EPSRC Grant EP/R512904/1 as well as the Royal Society Research Grant RSGR1180353. L.P.-P. acknowledges Generalitat Valenciana for her APOSTD2017 fellowship. This work was also partially sponsored by the CO2Chem through the EPSRC Grant EP/P026435/1. |
URI: | http://hdl.handle.net/10045/105407 |
ISSN: | 2168-0485 |
DOI: | 10.1021/acssuschemeng.0c00551 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Drets: | © 2020 American Chemical Society |
Revisió científica: | si |
Versió de l'editor: | https://doi.org/10.1021/acssuschemeng.0c00551 |
Apareix a la col·lecció: | INV - LMA - Artículos de Revistas |
Arxius per aquest ítem:
Arxiu | Descripció | Tamany | Format | |
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Le-Sache_etal_2020_ACSSustainableChemEng_final.pdf | Versión final (acceso restringido) | 2,44 MB | Adobe PDF | Obrir Sol·licitar una còpia |
Le-Sache_etal_2020_ACSSustainableChemEng_accepted.pdf | Accepted Manuscript (acceso abierto) | 499,17 kB | Adobe PDF | Obrir Vista prèvia |
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