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Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents

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dc.contributorAlternative Methodologies In Chemistry (AMIC)es_ES
dc.contributorNuevos Materiales y Catalizadores (MATCAT)es_ES
dc.contributorCatálisis Estereoselectiva en Síntesis Orgánica (CESO)es_ES
dc.contributor.authorMarset, Xavier-
dc.contributor.authorSaavedra, Beatriz-
dc.contributor.authorGonzález-Gallardo, Nerea-
dc.contributor.authorBeaton, Alexander-
dc.contributor.authorLeón, Martín M.-
dc.contributor.authorLuna, Raúl-
dc.contributor.authorRamón, Diego J.-
dc.contributor.authorGuillena, Gabriela-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Orgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Síntesis Orgánicaes_ES
dc.date.accessioned2019-10-23T07:59:31Z-
dc.date.available2019-10-23T07:59:31Z-
dc.date.issued2019-10-23-
dc.identifier.citationMarset X, Saavedra B, González-Gallardo N, Beaton A, León MM, Luna R, Ramón DJ and Guillena G (2019) Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents. Front. Chem. 7:700. doi: 10.3389/fchem.2019.00700es_ES
dc.identifier.issn2296-2646-
dc.identifier.urihttp://hdl.handle.net/10045/97811-
dc.description.abstractA strong σ-donor mesoionic carbene ligand has been synthesized and applied to four different palladium-catalyzed cross-coupling transformations, proving the catalyst/medium compatibility and the increased activity of this system over previous reports in Deep Eutectic Solvent medium. Some cross-coupling processes could be carried out at room temperature and using aryl chlorides as starting materials. The possible implementation of multistep synthesis in eutectic mixtures has also been explored. The presence of palladium nanoparticles in the reaction media has been evaluated and correlated to the observed activity.es_ES
dc.description.sponsorshipThis work was supported by the Spanish Ministerio de Economía, Industria y Competitividad (CTQ2015-66624-P and PGC2018-096616-B-I00) and the University of Alicante (VIGROB-316).es_ES
dc.languageenges_ES
dc.publisherFrontiers Mediaes_ES
dc.rights© 2019 Marset, Saavedra, González-Gallardo, Beaton, León, Luna, Ramón and Guillena. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.es_ES
dc.subjectMesoionic carbenees_ES
dc.subjectPalladiumes_ES
dc.subjectDeep Eutectic Solventes_ES
dc.subjectSustainabilityes_ES
dc.subjectCross-coupling reactiones_ES
dc.subject.otherQuímica Orgánicaes_ES
dc.titlePalladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solventses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.peerreviewedsies_ES
dc.identifier.doi10.3389/fchem.2019.00700-
dc.relation.publisherversionhttps://doi.org/10.3389/fchem.2019.00700es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2015-66624-P-
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-096616-B-I00-
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