Nitrogen-Doped Seamless Activated Carbon Electrode with Excellent Durability for Electric Double Layer Capacitor
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http://hdl.handle.net/10045/105868
Títol: | Nitrogen-Doped Seamless Activated Carbon Electrode with Excellent Durability for Electric Double Layer Capacitor |
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Autors: | Tagaya, Tomomi | Hatakeyama, Yoshikiyo | Shiraishi, Soshi | Tsukada, Hidehiko | Mostazo-López, María José | Morallon, Emilia | Cazorla-Amorós, Diego |
Grups d'investigació o GITE: | Materiales Carbonosos y Medio Ambiente | Electrocatálisis y Electroquímica de Polímeros |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Materiales |
Paraules clau: | Electric double layer capacitor | Seamless activated carbon electrode | Nitrogen-doping | Electrochemical durability |
Àrees de coneixement: | Química Inorgánica | Química Física |
Data de publicació: | 14-d’abril-2020 |
Editor: | IOP Publishing |
Citació bibliogràfica: | Journal of The Electrochemical Society. 2020, 167(6): 060523. doi:10.1149/1945-7111/ab8403 |
Resum: | The electric double layer capacitor (EDLC) using a seamless activated carbon electrode shows an excellent durability against high voltage charging compared to the conventional activated carbon composite electrode. In this study, the authors focused on nitrogen-doping as a surface modification to further improve the electrochemical durability of the seamless electrode. The EDLC using the nitrogen-doped seamless activated carbon electrode achieved the volumetric capacitance of 18 F cm−3 (based on the galvanostatic method, 80 mA g−1, 0–2.5 V, 40 °C) and the capacitance retention of 83% after the float durability test (3.5 V, 70 °C, 100 h) using a typical propylene carbonate electrolyte. The volumetric capacitance is comparable to that (14 F cm−3) of the conventional activated carbon, such as YP50F, and the retention is much higher than that (76%) of the pristine seamless activated carbon. The authors concluded that the extremely excellent durability of the nitrogen-doped seamless activated carbon electrode is due to (i) the stable electric network arising from the binder-less monolithic structure and (ii) nitrogen surface functionalities that suppresses micropore blocking and internal resistance change caused by electrochemical decomposition deposits. |
Patrocinadors: | This work is partially supported by JSPS KAKENHI Grant. No. JP17H03123 and Gunma University Element Functional Science Project in Japan. |
URI: | http://hdl.handle.net/10045/105868 |
ISSN: | 0013-4651 (Print) | 1945-7111 (Online) |
DOI: | 10.1149/1945-7111/ab8403 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Drets: | © 2020 The Electrochemical Society ("ECS"). Published on behalf of ECS by IOP Publishing Limited |
Revisió científica: | si |
Versió de l'editor: | https://doi.org/10.1149/1945-7111/ab8403 |
Apareix a la col·lecció: | INV - GEPE - Artículos de Revistas INV - MCMA - Artículos de Revistas |
Arxius per aquest ítem:
Arxiu | Descripció | Tamany | Format | |
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Tagaya_etal_2020_JElectrochemSoc_final.pdf | Versión final (acceso restringido) | 1,17 MB | Adobe PDF | Obrir Sol·licitar una còpia |
Tagaya_etal_2020_JElectrochemSoc_preprint.pdf | Preprint (acceso abierto) | 724,68 kB | Adobe PDF | Obrir Vista prèvia |
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