Organocatalyzed Assembly of Chlorinated Quaternary Stereogenic Centers
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http://hdl.handle.net/10045/64507
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Campo DC | Valor | Idioma |
---|---|---|
dc.contributor | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) | es_ES |
dc.contributor | Nuevos Materiales y Catalizadores (MATCAT) | es_ES |
dc.contributor.author | Gómez-Martínez, Melania | - |
dc.contributor.author | Alonso, Diego A. | - |
dc.contributor.author | Pastor, Isidro M. | - |
dc.contributor.author | Guillena, Gabriela | - |
dc.contributor.author | Baeza, Alejandro | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Orgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica | es_ES |
dc.date.accessioned | 2017-03-16T11:14:24Z | - |
dc.date.available | 2017-03-16T11:14:24Z | - |
dc.date.issued | 2016-12 | - |
dc.identifier.citation | Asian Journal of Organic Chemistry. 2016, 5(12): 1428-1437. doi:10.1002/ajoc.201600404 | es_ES |
dc.identifier.issn | 2193-5807 (Print) | - |
dc.identifier.issn | 2193-5815 (Online) | - |
dc.identifier.uri | http://hdl.handle.net/10045/64507 | - |
dc.description.abstract | The catalytic asymmetric construction of chiral quaternary stereocenters is a continual area of research for organic chemists. In this sense, when a chlorine atom is introduced to a quaternary stereocenter, the synthetic difficulty of the resulting molecule increases along with its significance. This is true not only because of the intrinsic interest in such chlorinated molecules but also because they are highly valuable chiral building blocks in organic synthesis, as they can be converted into more complex molecules by a SN2 displacement reaction. Among the different strategies to create chlorinated quaternary stereogenic centers, organocatalysis has played a pivotal role over the past decade. In this review, a comprehensive analysis of such organocatalyzed transformations with a focus on the α-chlorination of carbonyl compounds is presented. | es_ES |
dc.description.sponsorship | Financial support from the University of Alicante (VIGROB-173) and the Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) is acknowledged. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Wiley-VCH Verlag GmbH & Co. KGaA | es_ES |
dc.rights | © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
dc.subject | Asymmetric catalysis | es_ES |
dc.subject | Carbonyl compounds | es_ES |
dc.subject | Chlorine | es_ES |
dc.subject | Organocatalysis | es_ES |
dc.subject | Quaternary stereocenters | es_ES |
dc.subject.other | Química Orgánica | es_ES |
dc.title | Organocatalyzed Assembly of Chlorinated Quaternary Stereogenic Centers | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1002/ajoc.201600404 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/ajoc.201600404 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-66624-P | - |
Aparece en las colecciones: | INV - CESO - Artículos de Revistas INV - MATCAT - Artículos de Revistas INV - AMIC - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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2016_Gomez-Martinez_etal_AsianJOrgChem_final.pdf | Versión final (acceso restringido) | 1,11 MB | Adobe PDF | Abrir Solicitar una copia |
2016_Gomez-Martinez_etal_AsianJOrgChem_rev.pdf | Versión revisada (acceso abierto) | 3,13 MB | Adobe PDF | Abrir Vista previa |
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