Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments
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Título: | Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments |
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Autor/es: | Alonso, Diego A. | Baeza, Alejandro | Chinchilla, Rafael | Gómez, Cecilia | Guillena, Gabriela | Pastor, Isidro M. | Ramón, Diego J. |
Grupo/s de investigación o GITE: | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) | Nuevos Materiales y Catalizadores (MATCAT) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Palladium | Catalysis | Sonogashira reaction | Supported reagents | Cross-coupling reactions |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 11-may-2018 |
Editor: | MDPI |
Cita bibliográfica: | Alonso DA, Baeza A, Chinchilla R, Gómez C, Guillena G, Pastor IM, Ramón DJ. Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments. Catalysts. 2018; 8(5):202. doi:10.3390/catal8050202 |
Resumen: | The Sonogashira cross-coupling reaction is the most frequently employed synthetic procedure for the preparation of arylated alkynes, which are important conjugated compounds with multiple applications. Despite of their rather high price, this reaction is usually catalyzed by palladium species, making the recovery and reuse of the catalyst an interesting topic, mainly for industrial purposes. Easy recycle can be achieved anchoring the palladium catalyst to a separable support. This review shows recent developments in the use of palladium species anchored to different solid supports as recoverable catalysts for Sonogashira cross-coupling reactions. |
Patrocinador/es: | We thank the financial support from the Spanish Ministerio de Economía, Industria y Competitividad (CTQ2015-66624-P) and the University of Alicante (UAUSTI16-03, AUSTI16-10, VIGROB-173, and VIGROB-285). |
URI: | http://hdl.handle.net/10045/75493 |
ISSN: | 2073-4344 |
DOI: | 10.3390/catal8050202 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.3390/catal8050202 |
Aparece en las colecciones: | INV - MATCAT - Artículos de Revistas INV - CESO - Artículos de Revistas INV - AMIC - Artículos de Revistas |
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2018_Alonso_etal_Catalysts.pdf | 13,95 MB | Adobe PDF | Abrir Vista previa | |
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