One-pot hydrothermal synthesis of FeNbO4 microspheres for effective sonocatalysis
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Título: | One-pot hydrothermal synthesis of FeNbO4 microspheres for effective sonocatalysis |
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Autor/es: | He, Min | Li, Defa | Liu, Yu | Li, Taohai | Li, Feng | Fernández-Catalá, Javier | Cao, Wei |
Grupo/s de investigación o GITE: | Materiales Carbonosos y Medio Ambiente |
Centro, Departamento o Servicio: | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | FeNbO4 | Fenton-like reaction | Acid orange 7 (AO7) | Sonocatalysis |
Fecha de publicación: | 11-mar-2024 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | New Journal of Chemistry. 2024, 48: 6704-6713. https://doi.org/10.1039/D3NJ05239G |
Resumen: | FeNbO4 sonocatalysts were successfully synthesized by a simple hydrothermal route at pH conditions of 3, 5, 7, 9 and 11. The catalysts were characterized by XRD, XPS, TEM, SEM, N2 adsorption and DRS to analyse the effect of pH parameters on the physicochemical properties of the materials during hydrothermal synthesis. The sonocatalytic activity of FeNbO4 microspheres was evaluated by using acid orange 7 (AO7) as the simulated contaminant. The experimental results showed that the best sonocatalytic degradation ratio (97.45%) of organic dyes could be obtained when the conditions of initial AO7 concentration of 10 mg/L, ultrasonic power of 200W, catalyst dosage of 1.0g/L, pH=3. Moreover, the sonocatalysts demonstrated consistent durability and stability across multiple test cycles. After active species capture experiments and calculation of the energy band, a possible mechanism was proposed based on the special Fenton-like mechanism and the dissociation of H2O2. The research shows that FeNbO4 microspheres can be used as sonocatalysts for the purification of organic wastewater, which has a promising application prospect. |
Patrocinador/es: | Financial supports from Xiangtan University, China Scholarship Council, European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 101002219), European Union-Next Generation EU, MINECO, and University of Alicante for a postdoctoral researcher grant (MARSALAS21-09) are acknowledged. |
URI: | http://hdl.handle.net/10045/141430 |
ISSN: | 1144-0546 (Print) | 1369-9261 (Online) |
DOI: | 10.1039/D3NJ05239G |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1039/D3NJ05239G |
Aparece en las colecciones: | INV - MCMA - Artículos de Revistas Investigaciones financiadas por la UE |
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