Tunable hybrid zeolites prepared by partial interconversion
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/132614
| Título: | Tunable hybrid zeolites prepared by partial interconversion |
|---|---|
| Autor/es: | Mendoza-Castro, Monica J. | Qie, Zhipeng | Fan, Xiaolei | Linares, Noemi | Garcia-Martinez, Javier |
| Grupo/s de investigación o GITE: | Laboratorio de Nanotecnología Molecular (NANOMOL) |
| Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica |
| Palabras clave: | Hybrid Zeolites | Interconversion | Catalysts | FAU | MFI |
| Fecha de publicación: | 6-mar-2023 |
| Editor: | Springer Nature |
| Cita bibliográfica: | Nature Communications. 2023, 14:1256. https://doi.org/10.1038/s41467-023-36502-3 |
| Resumen: | Zeolite interconversion is a widely used strategy due to its unique advantages in the synthesis of some zeolites. By using a long-chain quaternary amine as both a structure-directing agent and porogen, we have produced superior catalysts, which we named Hybrid Zeolites, as their structures are made of building units of different zeolite types. The properties of these materials can be conveniently tuned, and their catalytic performance can be optimized simply by stopping the interconversion at different times. For cracking the 1,3,5-triisopropylbenzene, Hybrid Zeolites made of FAU and MFI units show a 5-fold increase in selectivity towards the desired product, that is, 1,3-diisopropylbenzene, compared to the commercial FAU, and a 7-fold increase in conversion at constant selectivity compared to MFI zeolite. |
| Patrocinador/es: | This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No 872102. M.J.M. thanks the Generalitat Valenciana for a Ph.D. fellowship (GRISOLIAP/2020/165). Z.Q. thanks the financial support of the China Scholarship Council for his Ph.D. secondment at The University of Manchester (CSC file no. 201906120207). |
| URI: | http://hdl.handle.net/10045/132614 |
| ISSN: | 2041-1723 |
| DOI: | 10.1038/s41467-023-36502-3 |
| Idioma: | eng |
| Tipo: | info:eu-repo/semantics/article |
| Derechos: | © The Author(s) 2023. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| Revisión científica: | si |
| Versión del editor: | https://doi.org/10.1038/s41467-023-36502-3 |
| Aparece en las colecciones: | Investigaciones financiadas por la UE INV - NANOMOL - Artículos de Revistas |
Archivos en este ítem:
| Archivo | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
 Mendoza-Castro_etal_2023_NatCommun.pdf | 1,69 MB | Adobe PDF | Abrir Vista previa | |
Ver citas en Google Académico
Este ítem está licenciado bajo Licencia Creative Commons
