Glycerol electro-oxidation at Pt in alkaline media: influence of mass transport and cations
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Título: | Glycerol electro-oxidation at Pt in alkaline media: influence of mass transport and cations |
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Autor/es: | Melle, Gabriel | Souza, Matheus B.C. de | Santiago, Patrícia V.B. | Corradini, Patricia Gon | Mascaro, Lucia Helena | Fernández, Pablo S. | Sitta, Elton |
Centro, Departamento o Servicio: | Universidad de Alicante. Instituto Universitario de Electroquímica |
Palabras clave: | Glycerol electro-oxidation | Platinum | Cation effect | Oscillation | Mass-transport |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | 28-sep-2021 |
Editor: | Elsevier |
Cita bibliográfica: | Electrochimica Acta. 2021, 398: 139318. https://doi.org/10.1016/j.electacta.2021.139318 |
Resumen: | Glycerol is an important biomass-derived product with potential to be applied on energy converting systems or as platform molecule in electrosynthesis. In this work we studied the glycerol oxidation reaction (GOR) in alkaline media containing distinct alkaline cations and controlling the mass transport. The cyclic voltammograms were deconvoluted into three processes and the changes in the charge of each process revealed that mass transport affects the GOR in a complex matter, depending on both applied potential and electrolyte cation. Regardless of the cation on supporting electrolyte, high-performance liquid chromatography (HPLC) analysis revealed the production of glycerate and lactate during GOR. Finally, potential oscillations under current control were mapped, highlighting the influence of both cations and mass transport, even in the systems with very similar behavior under potential control. |
Patrocinador/es: | The authors thank to the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001 and the Conselho Nacional de Pesquisa e Desenvolvimento (CNPq), for fellowships and grants (#430426/2018-6). The authors also thank the São Paulo Research Foundation (FAPESP) (Grants #2013/07296-2, #2014/50249-8, #2017/11986-5, #2018/20952-0 and #2019/00305-2), Shell, and the strategic importance of the support given by ANP (Brazil's National Oil, Natural Gas and Biofuels Agency) through the R&D levy regulation. |
URI: | http://hdl.handle.net/10045/119365 |
ISSN: | 0013-4686 (Print) | 1873-3859 (Online) |
DOI: | 10.1016/j.electacta.2021.139318 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2021 Elsevier Ltd. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.electacta.2021.139318 |
Aparece en las colecciones: | Personal Investigador sin Adscripción a Grupo INV - EQSUP - Artículos de Revistas |
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Melle_etal_2021_ElectrochimActa_final.pdf | Versión final (acceso restringido) | 2,03 MB | Adobe PDF | Abrir Solicitar una copia |
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