Surfactant-Templating of Zeolites: From Design to Application
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/109573
Título: | Surfactant-Templating of Zeolites: From Design to Application |
---|---|
Autor/es: | Sachse, Alexander | Garcia-Martinez, Javier |
Grupo/s de investigación o GITE: | Laboratorio de Nanotecnología Molecular (NANOMOL) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica |
Palabras clave: | Surfactant-templating | Zeolites |
Área/s de conocimiento: | Química Inorgánica |
Fecha de publicación: | 4-abr-2017 |
Editor: | American Chemical Society |
Cita bibliográfica: | Chemistry of Materials. 2017, 29(9): 3827-3853. https://doi.org/10.1021/acs.chemmater.7b00599 |
Resumen: | Surfactant-templating is one of the most effective and versatile synthetic strategies for the construction of well-defined porous architectures in solids. Though the principles of molecular self-assembly were disclosed in biological systems long since, the use of amphiphiles to generate porous architectures in inorganic matter has merely emerged at the very end of the 20th century. The present review proposes a voyage from the early developments of surfactant-templating for designing ordered mesoporous solids to the application of its principles for the generation of hierarchical zeolites. A thorough overview on the various strategies employing supramolecular chemistry to designing mesoporosity in zeolites is presented. The efficiency of the postsynthetic surfactant-templating approach in bridging the gap between zeolites and amorphous mesoporous molecular sieves is depicted through assessing their key properties, such as hydrothermal stability, texture and acidity. Finally, the impact of hierarchical zeolites in the industry will be highlighted through a review of the catalytic performance of mesostructured zeolites as components of FCC catalysts in various refineries. |
Patrocinador/es: | The authors acknowledge the EU and MINECO through the CAPITA Project WAVES (EP7-NMP-266543 and PCIN-2013-175) and FEDER for financial support. |
URI: | http://hdl.handle.net/10045/109573 |
ISSN: | 0897-4756 (Print) | 1520-5002 (Online) |
DOI: | 10.1021/acs.chemmater.7b00599 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2017 American Chemical Society |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1021/acs.chemmater.7b00599 |
Aparece en las colecciones: | INV - NANOMOL - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Sachse_Garcia-Martinez_2017_ChemMater_final.pdf | Versión final (acceso restringido) | 6,12 MB | Adobe PDF | Abrir Solicitar una copia |
Sachse_Garcia-Martinez_2017_ChemMater_accepted.pdf | Accepted Manuscript (acceso abierto) | 4,96 MB | Adobe PDF | Abrir Vista previa |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.