Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties
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Título: | Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties |
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Autor/es: | Micó-Vicent, Bàrbara | Jordán, Jorge | Perales, Esther | Martínez-Verdú, Francisco M. | Cases, Francisco |
Grupo/s de investigación o GITE: | Visión y Color |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Óptica, Farmacología y Anatomía |
Palabras clave: | Hybrid pigments | Natural dyes | Biopolymer | Taguchi | FTIR | Fastness |
Área/s de conocimiento: | Óptica |
Fecha de publicación: | 9-ene-2019 |
Editor: | MDPI |
Cita bibliográfica: | Micó-Vicent B, Jordán J, Perales E, Martínez-Verdú FM, Cases F. Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties. Coatings. 2019; 9(1):34. doi:10.3390/coatings9010034 |
Resumen: | Interest in applications of natural dye applications has increased because of their antibacterial properties and the possibility of extracting them from nature and residues. Using nanoclays as hosts to reinforce natural dye properties has been successfully demonstrated. However, no one has attempted to optimize the polymer matrix and hybrid pigment properties at the same time to ensure the best final properties for bio-composite applications. Using a statistical design for experiments, we propose the best combination of modifiers with the best nanoclay as the host of three natural dyes: chlorophyll, β-carotene, and betanine. Using the L9 Taguchi designs, we learned both the influence of the nanoclay structure, and the addition moment of surfactant, mordant salt, and silane modifiers. FTIR, XRD, DTG, integration sphere spectrophotometer, and UV-aging tests were used to characterize the hybrid pigments and epoxy bioresin composites. The degradation temperatures of the three natural dyes rose and the reinforcement of the stability of three natural dyes to UV–Vis radiation exposure was demonstrated, which avoided the migration of these dyes from bioresin to wet ribbing. Optimal results were obtained with hydrotalcite clay (calcined or not) by using surfactant and mordant before the natural dye, and before or after silane. |
Patrocinador/es: | This research was funded by Spanish Agencia Estatal de Investigación (AEI) and the European Union (FEDER funds) (contract MAT2016-77742-C2-1-P) and Spanish Ministry of Economy and Competitiveness (project DPI2015-65814-R). |
URI: | http://hdl.handle.net/10045/85708 |
ISSN: | 2079-6412 |
DOI: | 10.3390/coatings9010034 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.3390/coatings9010034 |
Aparece en las colecciones: | INV - GVC - Artículos de Revistas |
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Archivo | Descripción | Tamaño | Formato | |
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2019_Mico-Vicent_etal_Coatings.pdf | 5,66 MB | Adobe PDF | Abrir Vista previa | |
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