Study of the LLE, VLE, and VLLE of the Ternary System Water + 1-Butanol + Isoamyl Alcohol at 101.3 kPa
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Title: | Study of the LLE, VLE, and VLLE of the Ternary System Water + 1-Butanol + Isoamyl Alcohol at 101.3 kPa |
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Authors: | Saquete Ferrándiz, María Dolores | Font, Alicia | Garcia-Cano, Jorge | Blasco, Inmaculada |
Research Group/s: | Equilibrio entre Fases | Procesado y Pirólisis de Polímeros |
Center, Department or Service: | Universidad de Alicante. Departamento de Ingeniería Química | Universidad de Alicante. Instituto Universitario de Ingeniería de los Procesos Químicos |
Keywords: | LLE | VLE | VLLE | 1butanol | Isoamyl alcohol | Water |
Knowledge Area: | Ingeniería Química |
Issue Date: | 11-Sep-2018 |
Publisher: | American Chemical Society |
Citation: | Journal of Chemical & Engineering Data. 2018. doi:10.1021/acs.jced.8b00308 |
Abstract: | The liquid–liquid equilibrium of the water + 1-butanol + isoamyl alcohol system at 303.15 and 313.15 K has been determined experimentally. The UNIQUAC, NRTL, and UNIFAC models have been employed to correlate and predict liquid–liquid equilibria (LLE) and compare them with the experimental data. Additionally, the vapor–liquid and vapor–liquid–liquid equilibria (VLE and VLLE, respectively) of this system have been determined using a modified Fischer LABODEST still. The data obtained have been used to correlate and obtain the binary interaction parameters for UNIQUAC and NRTL. The validity of the models to reproduce the VLE and VLLE data has been analyzed. |
Sponsor: | We thank the Conselleria d’Educació, Investigació, Cultura i Esport (Generalitat Valenciana) of Spain for the financial support of project AICO/2015/052. |
URI: | http://hdl.handle.net/10045/79667 |
ISSN: | 0021-9568 (Print) | 1520-5134 (Online) |
DOI: | 10.1021/acs.jced.8b00308 |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | © 2018 American Chemical Society |
Peer Review: | si |
Publisher version: | https://doi.org/10.1021/acs.jced.8b00308 |
Appears in Collections: | INV - GTP3 - Artículos de Investigación sobre Equilibrio entre Fases INV - EQF - Artículos de Revistas |
Files in This Item:
File | Description | Size | Format | |
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2018_Saquete_etal_JChemEngData_preprint.pdf | Preprint (acceso abierto) | 478,31 kB | Adobe PDF | Open Preview |
2018_Saquete_etal_JChemEngData_final.pdf | Versión final (acceso restringido) | 3,43 MB | Adobe PDF | Open Request a copy |
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