Comparative Study of Catalytic Systems Formed by Palladium and Acyl-Substituted Imidazolium Salts
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http://hdl.handle.net/10045/72662
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Camp Dublin Core | Valor | Idioma |
---|---|---|
dc.contributor | Nuevos Materiales y Catalizadores (MATCAT) | es_ES |
dc.contributor.author | Gisbert, Patricia | - |
dc.contributor.author | Trillo Alarcón, María Paz | - |
dc.contributor.author | Pastor, Isidro M. | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Orgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica | es_ES |
dc.date.accessioned | 2018-01-19T13:26:56Z | - |
dc.date.available | 2018-01-19T13:26:56Z | - |
dc.date.issued | 2018-01-23 | - |
dc.identifier.citation | ChemistrySelect. 2018, 3(3): 887-893. doi:10.1002/slct.201702818 | es_ES |
dc.identifier.issn | 2365-6549 | - |
dc.identifier.uri | http://hdl.handle.net/10045/72662 | - |
dc.description.abstract | Amino amides, which are readily accessible from amino acids, were used in the preparation of both monoamido and diamido functionalized imidazolium salts in very straightforward protocols. Different catalytic systems formed with palladium(II) acetate and acyl functionalized imidazolium salts were tested in the Matsuda-Heck reaction. The comparative study revealed that the presence of one carbamoyl moiety in the N-heterocyclic carbene precursor is more beneficial during the catalytic process. Thus, better activity was observed with the catalytic system formed using 3-benzyl-1-(N-phenylcarbamoylmethyl)imidazolium chloride in a 1:1 metal/ligand ratio. Moreover, this fact was evidenced by means of UV/vis studies. | es_ES |
dc.description.sponsorship | The Spanish Ministry (Ministerio de Economía y Competitividad CTQ2015-66624-P) and the University of Alicante (VIGROB-285) are gratefully acknowledged for financial support. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Wiley-VCH Verlag GmbH & Co. KGaA | es_ES |
dc.rights | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
dc.subject | Carbamoyl | es_ES |
dc.subject | Functionalized imidazolium | es_ES |
dc.subject | Matsuda-Heck reaction | es_ES |
dc.subject | N-heterocyclic carbene | es_ES |
dc.subject | Palladium | es_ES |
dc.subject.other | Química Orgánica | es_ES |
dc.title | Comparative Study of Catalytic Systems Formed by Palladium and Acyl-Substituted Imidazolium Salts | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1002/slct.201702818 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/slct.201702818 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-66624-P | - |
Apareix a la col·lecció: | INV - MATCAT - Artículos de Revistas INV - AMIC - Artículos de Revistas |
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2018_Gisbert_etal_ChemistrySelect_final.pdf | Versión final (acceso restringido) | 2,42 MB | Adobe PDF | Obrir Sol·licitar una còpia |
2018_Gisbert_etal_ChemistrySelect_revised.pdf | Versión revisada (acceso abierto) | 1,59 MB | Adobe PDF | Obrir Vista prèvia |
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