Support effects on SILP hybrid catalysts prepared with carbon materials and the RhCOD complex
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Campo DC | Valor | Idioma |
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dc.contributor | Materiales Carbonosos y Medio Ambiente | es_ES |
dc.contributor.author | Rufete Beneite, Mónica | - |
dc.contributor.author | Román-Martínez, M. Carmen | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Inorgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Materiales | es_ES |
dc.date.accessioned | 2017-02-07T13:20:30Z | - |
dc.date.available | 2017-02-07T13:20:30Z | - |
dc.date.issued | 2016-10-18 | - |
dc.identifier.citation | RSC Advances. 2016, 6: 100976-100983. doi:10.1039/C6RA22213G | es_ES |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | http://hdl.handle.net/10045/62696 | - |
dc.description.abstract | The Rh complex RhCOD has been immobilized on different carbon materials by means of the SILP methodology (Supported Ionic Liquid Phase) with the purpose of preparing hybrid catalysts (those combining the advantages of homogeneous and heterogeneous catalysis). The catalysts prepared in this work have been tested in the hydrogenation of cyclohexene showing good activity, and being all of them more active than an equivalent biphasic system. They are reusable without significant loss of activity in at least three runs. An important effect of the support properties, related to the pore texture and the surface chemistry, has been found. Likely, an appropriate combination of high supermicropore volume, high mesopore volume and a reach surface chemistry leads to the best results. The obtained results should stimulate analogous research on the challenging development of chiral SILP catalysts. | es_ES |
dc.description.sponsorship | The authors thank the MINECO and FEDER for financial support through projects MAT2012-32832 and CTQ2015-66080-R, and GV for project PROMETEOII/2014/010. M. R. B. thanks the FPI scholarship grant associated to project MAT2009-07150. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.rights | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | es_ES |
dc.subject | SILP methodology | es_ES |
dc.subject | Hybrid catalysts | es_ES |
dc.subject | Carbon materials | es_ES |
dc.subject | RhCOD complex | es_ES |
dc.subject.other | Química Inorgánica | es_ES |
dc.title | Support effects on SILP hybrid catalysts prepared with carbon materials and the RhCOD complex | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1039/C6RA22213G | - |
dc.relation.publisherversion | http://dx.doi.org/10.1039/C6RA22213G | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
Aparece en las colecciones: | INV - MCMA - Artículos de Revistas |
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