The electrochemical co-polymerization of p-aminodiphenylamine and aniline: effect of pH
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Título: | The electrochemical co-polymerization of p-aminodiphenylamine and aniline: effect of pH |
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Autor/es: | Cotarelo Méndez, María de los Ángeles | Huerta Arráez, Francisco | Quijada Tomás, César | Cases Iborra, Francisco Javier | Vázquez Picó, José Luis |
Grupo/s de investigación o GITE: | Electrocatálisis y Electroquímica de Polímeros |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad Politécnica de Valencia. Departamento de Ingeniería Textil y Papelera |
Palabras clave: | Aniline | 4-ADPA | Cyclic voltammetry | Co-polymerization |
Área/s de conocimiento: | Química Física | Ciencia de Materiales |
Fecha de creación: | 8-oct-2004 |
Fecha de publicación: | 20-ago-2004 |
Editor: | Elsevier |
Cita bibliográfica: | COTARELO MÉNDEZ, María de los Ángeles, et al. "The electrochemical co-polymerization of p-aminodiphenylamine and aniline: effect of pH". Synthetic Metals. Vol. 148, Issue 1 (3 Jan. 2005). ISSN 0379-6779, pp. 81-85 |
Resumen: | The electrochemical oxidation of p-aminodiphenylamine (4ADPA) in the presence of aniline in phosphate medium of pH ranging from 1 to 10.5 has been investigated. Mixtures of both monomers can be co-polymerized to produce electroactive poly aniline-co-4ADPA (Pan-4adpa) films if the pH of the medium is kept, approximately, within 3 and 9 and the upper potential limit is lower than the oxidation potential of aniline. Pan-4adpa growth rates are pH dependent and are also affected by the amount of polymeric material deposited on the electrode surface. It has been suggested the existence of a certain inhibition effect of both H+ and OH− on the polymerization reaction. Contrary to what is observed for those films synthesized at pH 5 and 7, the growth of Pan-4adpa at pH 8 seems to be an autocatalytic process until the inhibition of the polymerization reaction takes place. |
Patrocinador/es: | Ministerio de Ciencia y Tecnología MAT2001-1007, MAT2004-01479 y REN2001-2304-C02-02/TECNO |
URI: | http://hdl.handle.net/10045/2542 |
ISSN: | 0379-6779 |
DOI: | 10.1016/j.synthmet.2004.08.035 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1016/j.synthmet.2004.08.035 |
Aparece en las colecciones: | INV - GEPE - Artículos de Revistas |
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Synthetic Metals 148 (2005) 81–85.pdf | Versión final (acceso restringido) | 127,37 kB | Adobe PDF | Abrir Solicitar una copia |
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