Liquid-liquid-solid equilibria for the quaternary system water + ethanol + 1-pentanol + sodium chloride at 25 °C
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| Title: | Liquid-liquid-solid equilibria for the quaternary system water + ethanol + 1-pentanol + sodium chloride at 25 °C |
|---|---|
| Authors: | Olaya, Maria del Mar | Marcilla, Antonio | Botella Ramón, Alfredo |
| Research Group/s: | Procesado y Pirólisis de Polímeros |
| Center, Department or Service: | Universidad de Alicante. Departamento de Ingeniería Química |
| Keywords: | Liquid-liquid-solid equilibria | Data | Salting-out | Quaternary system | Ethanol | 1-pentanol | Sodium chloride |
| Knowledge Area: | Ingeniería Química |
| Issue Date: | 31-Mar-1999 |
| Publisher: | Elsevier |
| Citation: | OLAYA LÓPEZ, María del Mar; MARCILLA GOMIS, Antonio; BOTELLA RAMÓN, Alfredo. “Liquid-liquid-solid equilibria for the quaternary system water + ethanol + 1-pentanol + sodium chloride at 25 °C”. Fluid Phase Equilibria. Vol. 157, Issue 2 (31 March 1999). ISSN 0378-3812, pp. 197-211 |
| Abstract: | Salting-out effect can be used to improve the extraction of some solutes by modifying the solute distribution between two liquid phases. In this work we report the results obtained for the quaternary system water + ethanol + 1-pentanol + sodium chloride at 25 ºC. All equilibrium regions (one liquid, two liquids, one liquid + one solid and two liquids + one solid zones) have been systematically studied. Tie lines and tie-triangles data were measured, after separating the conjugated phases, determining the liquid components by Chromatography, and sodium chloride by gravimetrical methods and titration with AgNO3 depending on its concentration. Distribution and selectivity curves are represented to analyse the sodium chloride salt effect. Tie-lines and tie-triangles data have been correlated using a modification of the Eisen-Joffe equation. |
| Sponsor: | The authors wish to thank the DGES (Spain) for the financial help of the Project PB96-0338. |
| URI: | http://hdl.handle.net/10045/2251 |
| ISSN: | 0378-3812 |
| DOI: | 10.1016/S0378-3812(99)00042-4 |
| Language: | eng |
| Type: | info:eu-repo/semantics/article |
| Peer Review: | si |
| Publisher version: | http://dx.doi.org/10.1016/S0378-3812(99)00042-4 |
| Appears in Collections: | INV - GTP3 - Artículos de Investigación sobre Equilibrio entre Fases |
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