Stabilized Palladium Nanoparticles from Bis-(N-benzoylthiourea) Derived-PdII Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water
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| Título: | Stabilized Palladium Nanoparticles from Bis-(N-benzoylthiourea) Derived-PdII Complexes as Efficient Catalysts for Sustainable Cross-Coupling Reactions in Water |
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| Autor/es: | Poyraz, Samet | Dondas, H. Ali | Belveren, Samet | Tas, Senanur | Hidalgo-León, Raquel | Trujillo-Sierra, José | Rodríguez-Flórez, Lesly V. | Retamosa, Maria de Gracia | Sirvent, Ana | Gholinejad, Mohammad | Sobhani, Sara | Sansano, Jose M. |
| Grupo/s de investigación o GITE: | Síntesis Asimétrica (SINTAS) |
| Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Palabras clave: | Nanoparticles | Palladium | Suzuki | Heck | Hiyama | Buchwald–Hartwig | Hirao | Sonogashira | Water | Heterogeneous catalysis |
| Fecha de publicación: | 4-mar-2024 |
| Editor: | MDPI |
| Cita bibliográfica: | Molecules. 2024, 29(5): 1138. https://doi.org/10.3390/molecules29051138 |
| Resumen: | Stable palladium (II) complexes, incorporating a double (N-benzoylthiourea) arrangement bonded to a complex heterocyclic scaffold, are used as precursors of catalytic species able to promote Suzuki–Miyaura, Mizoroki–Heck, Hiyama, Buchwald–Hartwig, Hirao and Sonogashira–Hagihara cross-coupling transformations in water. These sustainable processes are chemoselective and very versatile. The nanoparticles responsible for these catalytic reactions were analyzed and studied. Their usefulness is demonstrated after several tests and analyses. The heterogeneous character of this species in water was also confirmed. |
| Patrocinador/es: | We gratefully acknowledge financial support from Çukurova University (Project nos. TSA-2023-16116, TSA-2022-15050 and TSA-2023-15939) and Mersin University (Project nos. 2020-1-AP4-3982)). A part of this work is a part of Samet POYRAZ’s Ph.D. thesis. We are also thankful for financial support from the Spanish Ministerio de Ciencia, Innovación y Universidades (RED2022-134287-T ORFEO CINQA and RED2022-134331-T CASI) the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2017-82935-P and PID2019-107268GB-I00), the Generalitat Valenciana (IDIFEDER/2021/013, GVA-COVID19/2021/079 and CIDEGENT/2020/058), Medalchemy S. L. (Medalchemy-22T) and the University of Alicante (VIGROB-068, UAUSTI21-05). LVR-F thanks Generalitat Valenciana for Grisolía’s fellowship (GRISOLIAP/2020/111). JT thanks Generalitat Valenciana for APOTI contract (CIAPOT/2021/23). |
| URI: | http://hdl.handle.net/10045/141429 |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/molecules29051138 |
| Idioma: | eng |
| Tipo: | info:eu-repo/semantics/article |
| Derechos: | © 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
| Revisión científica: | si |
| Versión del editor: | https://doi.org/10.3390/molecules29051138 |
| Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas |
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 Poyraz_etal_2024_Molecules.pdf | 4,46 MB | Adobe PDF | Abrir Vista previa | |
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