Fe-MIL-101 modified by isatin-Schiff-base-Co: a heterogeneous catalyst for C–C, C–O, C–N, and C–P cross coupling reactions
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Título: | Fe-MIL-101 modified by isatin-Schiff-base-Co: a heterogeneous catalyst for C–C, C–O, C–N, and C–P cross coupling reactions |
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Autor/es: | Rouzifar, Majid | Sobhani, Sara | Farrokhi, Alireza | Sansano, Jose M. |
Grupo/s de investigación o GITE: | Síntesis Asimétrica (SINTAS) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Heterogeneous catalyst | Fe-MIL-101 modified | Isatin-Schiff-base-Co | C–C | C–O | C–N | C–P | Cross coupling reactions |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 30-sep-2021 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | New Journal of Chemistry. 2021, 45: 19963-19976. https://doi.org/10.1039/D1NJ03468E |
Resumen: | A metal–organic framework functionalized with a cobalt-complex is prepared via post-synthetic modification of Fe-MIL-101-NH2. Initially, Fe-MIL-101-NH2 reacted with isatin to produce Fe-MIL-101-isatin-Schiff-base, which can anchor the cobalt by the addition of cobalt acetate. The resulting MOF-Co catalyst is characterized by employing multiple techniques. This new modified MOF acts as a heterogeneous and recyclable catalyst for efficient Ullmann, Buchwald–Hartwig, Hirao, Hiyama and Mizoroki–Heck cross-coupling reactions of several aryl halides/phenylboronic acid/phenyltosylate with phenols, anilines/heterocyclic amines, triethyl phosphite, triethoxyphenylsilane and alkenes and generates the expected coupling products in good to high yields. |
Patrocinador/es: | Financial support of this project from the University of Birjand Research Council is acknowledged. Access to the FESEM, EDX mapping, TEM and XPS facilities at the Department of Chemistry, University of Alicante, is appreciated. |
URI: | http://hdl.handle.net/10045/119154 |
ISSN: | 1144-0546 (Print) | 1369-9261 (Online) |
DOI: | 10.1039/D1NJ03468E |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021 |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1039/D1NJ03468E |
Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Rouzifar_etal_2021_NewJChem_final.pdf | Versión final (acceso restringido) | 6,06 MB | Adobe PDF | Abrir Solicitar una copia |
Rouzifar_etal_2021_NewJChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 2,96 MB | Adobe PDF | Abrir Vista previa |
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