Synthesis and characterization of polymer/V2O5 composites based on poly(2‐aminodiphenylamine)
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Título: | Synthesis and characterization of polymer/V2O5 composites based on poly(2‐aminodiphenylamine) |
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Autor/es: | Zenasni, Mouniya | Quintero-Jaime, Andrés Felipe | Benyoucef, Abdelghani | Benghalem, Abderezak |
Grupo/s de investigación o GITE: | Electrocatálisis y Electroquímica de Polímeros |
Centro, Departamento o Servicio: | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | 2-aminodiphenylamine | Aniline | Electrochemical properties | Nanocomposites | Vanadium oxide |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | mar-2021 |
Editor: | Wiley |
Cita bibliográfica: | Polymer Composites. 2021, 42(3): 1064-1074. https://doi.org/10.1002/pc.25909 |
Resumen: | Hybrid materials consisting of aniline (ANI) and/or 2‐aminodiphenylamine (PD) in the presence of V2O5 nanoparticles were synthesized by in‐situ chemical oxidative polymerization in one‐step. Physicochemical and electrochemical characterization confirmed that in the structure of the composites, intercalation between the polymer chains and the V2O5 slabs occurs. Optical properties study shows that the optical band gap of poly(ANI‐co‐PD)/V2O5 is lower than poly‐PD/V2O5. Thermal stability of the composites by thermogravimetric analysis was evaluated. Composites showed electrochemical activity with improved electron‐transfer of the redox species in the polymer observed by cyclic voltammetry. These results highlight the great influence of the V2O5 sheets and the polymer composition on the hybrid materials formation and properties. |
Patrocinador/es: | The authors wish to acknowledge the directorate General of Scientific Research and Technological Development (DGRSDT) (Algeria). Financial support from the Spanish Ministerio de Ciencia e Innovación (PID2019-105923RB-I00) is gratefully acknowledged. A.F.Q.J. gratefully acknowledges Generalitat Valenciana for the financial support through Santiago Grisolía grant (GRISOLIA/2016/084). |
URI: | http://hdl.handle.net/10045/113505 |
ISSN: | 0272-8397 (Print) | 1548-0569 (Online) |
DOI: | 10.1002/pc.25909 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2020 Society of Plastics Engineers |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1002/pc.25909 |
Aparece en las colecciones: | INV - GEPE - Artículos de Revistas |
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Archivo | Descripción | Tamaño | Formato | |
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Zenasni_etal_2021_PolymerComposites_final.pdf | Versión final (acceso restringido) | 2,65 MB | Adobe PDF | Abrir Solicitar una copia |
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