Oxidative Dehydrogenation of Ethylbenzene Over Poly(furfuryl alcohol)-Derived CMK-1 Carbon Replica
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/75412
| Título: | Oxidative Dehydrogenation of Ethylbenzene Over Poly(furfuryl alcohol)-Derived CMK-1 Carbon Replica |
|---|---|
| Autor/es: | Jarczewski, Sebastian | Drozdek, Marek | Wach, Anna | Dudek, Barbara | Kuśtrowski, Piotr | Casco, Mirian Elizabeth | Rodríguez Reinoso, Francisco |
| Grupo/s de investigación o GITE: | Materiales Avanzados |
| Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica |
| Palabras clave: | Ordered mesoporous carbons | Replication | CMK-1 | Oxidative dehydrogenation of ethylbenzene | Styrene |
| Área/s de conocimiento: | Química Inorgánica |
| Fecha de publicación: | jul-2016 |
| Editor: | Springer US |
| Cita bibliográfica: | Catalysis Letters. 2016, 146(7): 1231-1241. doi:10.1007/s10562-016-1748-z |
| Resumen: | Poly(furfuryl alcohol) was introduced into a pore system of MCM-48 silica by the precipitation polycondensation of furfuryl alcohol (FA). The complete filling of the pores without the deposition of significant amounts of polymer on the external surface of MCM-48 was obtained at the FA/MCM-48 mass ratio close to 1.0. The final structure of carbon replica was formed by subsequent carbonization and extraction of SiO2 with HF. The carbonization temperature strongly influenced the surface composition of the formed carbon replicas. The highest catalytic activity in the oxidative dehydrogenation of ethylbenzene was observed for CMK-1 with the highest concentration of phenol and carbonyl groups, recognized as active sites of the studied reaction. |
| Patrocinador/es: | This work was supported by the National Science Centre under the Grant No. 2013/09/B/ST5/03419. The research was carried out with the equipment purchased thanks to the financial support of the European Regional Development Fund in the framework of the Polish Innovation Economy Operational Program (contract No. POIG.02.01.00-12-023/08). |
| URI: | http://hdl.handle.net/10045/75412 |
| ISSN: | 1011-372X (Print) | 1572-879X (Online) |
| DOI: | 10.1007/s10562-016-1748-z |
| Idioma: | eng |
| Tipo: | info:eu-repo/semantics/article |
| Derechos: | © The Author(s) 2016. Open Access. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
| Revisión científica: | si |
| Versión del editor: | https://doi.org/10.1007/s10562-016-1748-z |
| Aparece en las colecciones: | INV - LMA - Artículos de Revistas |
Archivos en este ítem:
| Archivo | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
 2016_Jarczewski_etal_CatalLett.pdf | 871,14 kB | Adobe PDF | Abrir Vista previa | |
Ver citas en Google Académico
Este ítem está licenciado bajo Licencia Creative Commons
