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IR and electrochemical synthesis and characterization of thin films of PEDOT grown on platinum single crystal electrodes in [EMMIM]Tf2N ionic liquid

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dc.contributorElectroquímica de Superficieses
dc.contributor.authorSandoval, Andrea P.-
dc.contributor.authorSuárez-Herrera, Marco F.-
dc.contributor.authorFeliu, Juan M.-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Físicaes
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Electroquímicaes
dc.date.accessioned2015-06-17T12:18:09Z-
dc.date.available2015-06-17T12:18:09Z-
dc.date.issued2015-03-13-
dc.identifier.citationBeilstein Journal of Organic Chemistry. 2015, 11: 348-357. doi:10.3762/bjoc.11.40es
dc.identifier.issn1860-5397-
dc.identifier.urihttp://hdl.handle.net/10045/47681-
dc.description.abstractThin films of PEDOT synthesized on platinum single electrodes in contact with the ionic liquid 1-ethyl-2,3-dimethylimidazolium triflimide ([EMMIM]Tf2N) were studied by cyclic voltammetry, chronoamperometry, infrared spectroscopy and atomic force microscopy. It was found that the polymer grows faster on Pt(111) than on Pt(110) or Pt(100) and that the redox reactions associated with the PEDOT p-doping process are much more reversible in [EMMIM]Tf2N than in acetonitrile. Finally, the ion exchange and charge carriers’ formation during the p-doping reaction of PEDOT were studied using in situ FTIR spectroscopy.es
dc.description.sponsorshipAPS acknowledges the scholarship “Estudiantes sobresalientes de posgrado” at the “Universidad Nacional de Colombia (UNAL)” and COLCIENCIAS National Doctoral Scholarship (567). MFS acknowledges support of UNAL (Research Project 19030). JMF thanks MINECO (Spain) support through project CTQ2013-44083-P and Generalitat Valenciana (Feder) through project PROMETEOII/2014/013.es
dc.languageenges
dc.publisherBeilstein-Institutes
dc.rightsThis is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc).es
dc.subjectAFMes
dc.subject[EMMIM]Tf2N ionic liquides
dc.subjectIn situ IRes
dc.subjectPEDOTes
dc.subjectPt single crystalses
dc.subject.otherQuímica Físicaes
dc.titleIR and electrochemical synthesis and characterization of thin films of PEDOT grown on platinum single crystal electrodes in [EMMIM]Tf2N ionic liquides
dc.typeinfo:eu-repo/semantics/articlees
dc.peerreviewedsies
dc.identifier.doi10.3762/bjoc.11.40-
dc.relation.publisherversionhttp://dx.doi.org/10.3762/bjoc.11.40es
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2013-44083-P-
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