Desilication of TS-1 zeolite for the oxidation of bulky molecules

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Title: Desilication of TS-1 zeolite for the oxidation of bulky molecules
Authors: Silvestre Albero, Ana | Grau-Atienza, Aida | Serrano, Elena | Garcia-Martinez, Javier | Silvestre-Albero, Joaquín
Research Group/s: Materiales Avanzados | Laboratorio de Nanotecnología Molecular (NANOMOL)
Center, Department or Service: Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Desilication | Hierarchical catalysts | TS-1 | Epoxidation reactions
Knowledge Area: Química Inorgánica
Issue Date: 10-Jan-2014
Publisher: Elsevier
Citation: Catalysis Communications. 2014, 44: 35-39. doi:10.1016/j.catcom.2013.08.004
Abstract: A series of modified TS-1 samples have been produced by desilication of the original TS-1 (4 wt.% Ti) using a chemical treatment with NaOH. Desilicated TS-1 zeolites exhibit a large BET surface area together with a well-developed mesoporosity. The hierarchical catalysts from desilication of TS-1 zeolite show a good catalytic activity for the oxidation of small molecules and a significantly higher activity for the oxidation of bulky molecules.
URI: http://hdl.handle.net/10045/37737
ISSN: 1566-7367 (Print) | 1873-3905 (Online)
DOI: 10.1016/j.catcom.2013.08.004
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.catcom.2013.08.004
Appears in Collections:INV - LMA - Artículos de Revistas
INV - NANOMOL - Artículos de Revistas

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