Diastereoselective allylation and crotylation of N-tert-butanesulfinyl imines with allylic alcohols
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| Campo DC | Valor | Idioma |
|---|---|---|
| dc.contributor | Síntesis Asimétrica (SINTAS) | es |
| dc.contributor.author | Soares do Rego Barros, Olga | - |
| dc.contributor.author | Sirvent Pérez, Juan Alberto | - |
| dc.contributor.author | Foubelo, Francisco | - |
| dc.contributor.author | Yus, Miguel | - |
| dc.contributor.other | Universidad de Alicante. Departamento de Química Orgánica | es |
| dc.contributor.other | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica | es |
| dc.date.accessioned | 2014-05-12T12:42:45Z | - |
| dc.date.available | 2014-05-12T12:42:45Z | - |
| dc.date.issued | 2014-04-24 | - |
| dc.identifier.citation | Chemical Communications. 2014, 50: 6898-6901. doi:10.1039/C4CC02317J | es |
| dc.identifier.issn | 1359-7345 (Print) | - |
| dc.identifier.issn | 1364-548X (Online) | - |
| dc.identifier.uri | http://hdl.handle.net/10045/37069 | - |
| dc.description.abstract | The palladium-catalyzed allylation of N-tert-butanesulfinyl imines with allylic alcohols in the presence of InI as reducing reagent takes place with high diastereoselectivity in reasonable yields. The reaction with crotyl alcohol is totally regioselective, leading to the anti-diastereomer as the main reaction product. | es |
| dc.description.sponsorship | Spanish Ministerio de Ciencia e Innovación (Grant No. CTQ2011-24165), the Generalitat Valenciana (Grant No. PROMETEO/2009/039 and FEDER) and the University of Alicante. OSRB thanks CNPq of Brazil for a fellowship. | es |
| dc.language | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.rights | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence | es |
| dc.subject | N-tert-butanesulfinyl imines | es |
| dc.subject | Palladium-catalyzed allylation | es |
| dc.subject | Diastereoselectivity | es |
| dc.subject | Allylic alcohols | es |
| dc.subject.other | Química Orgánica | es |
| dc.title | Diastereoselective allylation and crotylation of N-tert-butanesulfinyl imines with allylic alcohols | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.peerreviewed | si | es |
| dc.identifier.doi | 10.1039/C4CC02317J | - |
| dc.relation.publisherversion | http://dx.doi.org/10.1039/C4CC02317J | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN//CTQ2011-24165 | - |
| Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas | |
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| Archivo | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
 2014_Soares_etal_ChemComm.pdf | 1,14 MB | Adobe PDF | Abrir Vista previa | |
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