Silica extracts from fly ash modified via sol-gel methods and functionalized with CMPO for potential scavenging of rare earth elements La3⁺ and Ce3⁺
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Título: | Silica extracts from fly ash modified via sol-gel methods and functionalized with CMPO for potential scavenging of rare earth elements La3⁺ and Ce3⁺ |
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Autor/es: | Gómez, Mauricio | Pizarro, Jaime | Díaz, Carlos | Ortiz, Claudia | Castillo, Ximena | Navlani-García, Miriam | Cazorla-Amorós, Diego |
Grupo/s de investigación o GITE: | Materiales Carbonosos y Medio Ambiente |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Rare earth | Lanthanum | Cerium | Adsorption | Mesoporous materials | Carbamoyl methyl phosphine |
Fecha de publicación: | 3-abr-2024 |
Editor: | Elsevier |
Cita bibliográfica: | Materials Chemistry and Physics. 2024, 318: 129161. https://doi.org/10.1016/j.matchemphys.2024.129161 |
Resumen: | A mesoporous material was synthesized using silica extracts from fly ash and its properties were studied. Subsequently, it was functionalized with carbamoylmethylphosphine oxide (CMPO) to capture La3+ and Ce3+. The developed mesoporous material was obtained by the sol-gel method and was called Si-MMS (siliceous mesoporous materials), subsequently functionalized with APTMS (1-(2-aminoethyl)-3-aminopropyl trimethoxysilane) in a reflux system, which led to the synthesis of Si-MMS-APTMS. This derivative was modified with carbonyldiimidazole (CDI) and diethylphosphonoacetic acid, which finally resulted in the synthesis of Si-MMS-CMPO as the final product. The materials were characterized by DRIFT, XRD, SEM-EDS, TEM, XPS, elemental analysis and nitrogen isotherms at −196 °C, confirming that the synthesis and subsequent modification of the mesoporous structure was successful. Adsorption studies in batch systems indicated that the optimal pH for La3+ was 6, the Langmuir isotherm model and the non-linear Sips models were perfectly fitted and the best fitting kinetics is the Elovich model. For Ce3+ the optimal pH was 7.5, the non-linear Sips isotherm fit the best and the non-linear Pseudo-second order kinetics was the mechanism that best represents the adsorption. The maximum experimental adsorption capacity qe of La3+ was 17.00 mg g−1 and for Ce3+ was 30.09 mg g−1. In both cases, the rapid adsorption suggests an open porous matrix that facilitates the formation of chelates between the adsorbates and the phosphoryl group -PO32-. |
Patrocinador/es: | The authors acknowledge the financial support of this project by Fondef Grant ID18I10229, Fondef Grant ID20I10356; PostDoc_Dicyt code USA2055 Vicerrectoría de Investigación, Desarrollo e Innovación Universidad de Santiago de Chile; Dicyt Grant code 092112PK Vicerrectoría de Investigación, Desarrollo e Innovación Universidad de Santiago de Chile; Generalitat Valenciana (CIPROM/2021/70), Ministerio de Ciencia e Innovación (PID2021-123079OB-I00) Spain, and Proyecto ANID Fondecyt Postdoctoral Grant 3210179. |
URI: | http://hdl.handle.net/10045/142158 |
ISSN: | 0254-0584 (Print) | 1879-3312 (Online) |
DOI: | 10.1016/j.matchemphys.2024.129161 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2024 Elsevier B.V. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.matchemphys.2024.129161 |
Aparece en las colecciones: | INV - MCMA - Artículos de Revistas |
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Gomez_etal_2024_MaterChemPhys_final.pdf | Versión final (acceso restringido) | 5,66 MB | Adobe PDF | Abrir Solicitar una copia |
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