Exploring the Effects Behind the Outstanding Catalytic Performance of PdAg Catalysts Supported on Almond Shell-Derived Activated Carbon Towards the Dehydrogenation of Formic Acid
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/141847
Título: | Exploring the Effects Behind the Outstanding Catalytic Performance of PdAg Catalysts Supported on Almond Shell-Derived Activated Carbon Towards the Dehydrogenation of Formic Acid |
---|---|
Autor/es: | Riquelme-García, Paula | Chaparro-Garnica, Jessica | Navlani-García, Miriam | Cazorla-Amorós, Diego |
Grupo/s de investigación o GITE: | Materiales Carbonosos y Medio Ambiente |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Hydrogen | Formic acid | Biomass residues | PdAg alloy | Nitrogen functional groups |
Fecha de publicación: | 18-mar-2024 |
Editor: | Wiley-VCH GmbH |
Cita bibliográfica: | ChemCatChem. 2024. https://doi.org/10.1002/cctc.202400160 |
Resumen: | In this work, highly efficient carbon-supported Pd-based catalysts for formic acid dehydrogenation were synthesized by a straightforward wet impregnation-reduction method. The carbon support was obtained from a biomass residue (almond shell) prepared via H3PO4-assisted hydrothermal carbonization (HTC) and thermal activation. This carbon support was doped with nitrogen groups to study the effect on the electronic properties and catalytic performance of the catalysts. Investigating the formation of PdAg alloys with varying Pd:Ag molar ratios resulted in catalysts exhibiting enhanced catalytic activity compared to monometallic Pd counterparts. Notably, the Pd1Ag0.5/NAS catalyst displayed outstanding catalytic performance, achieving an initial TOF of 1716 h-1 (calculated in the first 3 minutes of reaction and expressed per mole of Pd) and maintaining substantial activity over 6 consecutive reaction cycles. This work elucidates the successful synthesis of effective catalysts, emphasizing the influence of nitrogen doping and PdAg alloy composition on catalytic behavior and stability. |
Patrocinador/es: | This work is part of the R+D+I project PID2021-123079OB-I00 funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe” and also the project TED2021-131324B-C22 funded by MCIN/AEI/ 10.13039/501100011033 and by the “European Union NextGenerationEU/PRTR. MNG would like to thank the grant RYC2021-034199-I funded by MCIN/AEI/10.13039/501100011033 and by “ESF Investing in your future”. |
URI: | http://hdl.handle.net/10045/141847 |
ISSN: | 1867-3880 (Print) | 1867-3899 (Online) |
DOI: | 10.1002/cctc.202400160 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2024 The Authors. ChemCatChem published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1002/cctc.202400160 |
Aparece en las colecciones: | INV - MCMA - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Riquelme-Garcia_etal_2024_ChemCatChem.pdf | 1,44 MB | Adobe PDF | Abrir Vista previa | |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.