Alkanes in Minisci-Type Reaction under Photocatalytic Conditions with Hydrogen Evolution
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/137893
| Título: | Alkanes in Minisci-Type Reaction under Photocatalytic Conditions with Hydrogen Evolution |
|---|---|
| Autor/es: | Laze, Loris | Quevedo-Flores, Beatriz | Bosque, Irene | Gonzalez-Gomez, Jose C. |
| Grupo/s de investigación o GITE: | Nuevos Materiales y Catalizadores (MATCAT) |
| Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Palabras clave: | Organic catalysts | Alkanes | Minisci-like reaction | Photocatalytic conditions | Hydrogen evolution |
| Fecha de publicación: | 11-oct-2023 |
| Editor: | American Chemical Society |
| Cita bibliográfica: | Organic Letters. 2023, 25(48): 8541-8546. https://doi.org/10.1021/acs.orglett.3c02619 |
| Resumen: | We report herein a protocol for the selective activation of C(sp3)–H bonds based on the interplay of two readily available organic catalysts and their successful implementation in cross-coupling azaarenes with alkanes. This Minisci-like reaction is promoted by visible light at room temperature and is free from chemical oxidants, metals, and chlorinated solvents. A wide range of substrates are compatible, including some bioactive molecules. Mechanistic studies support a dual catalytic cycle with H2 evolution. |
| Patrocinador/es: | This work was financially supported by the Generalitat Valenciana (SEJIGENT/2021/005 and IDIFEDER/2021/13) and the University of Alicante (GRE20-03-A granted to I. B.). |
| URI: | http://hdl.handle.net/10045/137893 |
| ISSN: | 1523-7060 (Print) | 1523-7052 (Online) |
| DOI: | 10.1021/acs.orglett.3c02619 |
| Idioma: | eng |
| Tipo: | info:eu-repo/semantics/article |
| Derechos: | © 2023 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0. |
| Revisión científica: | si |
| Versión del editor: | https://doi.org/10.1021/acs.orglett.3c02619 |
| Aparece en las colecciones: | INV - MATCAT - Artículos de Revistas |
Archivos en este ítem:
| Archivo | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
 Laze_etal_2023_OrgLett.pdf | 2,05 MB | Adobe PDF | Abrir Vista previa | |
Ver citas en Google Académico
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.