Nitrogen sites prevail over textural properties in N-doped carbons for the oxygen reduction reaction
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Título: | Nitrogen sites prevail over textural properties in N-doped carbons for the oxygen reduction reaction |
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Autor/es: | Quílez-Bermejo, Javier | Pérez-Rodríguez, Sara | Torres, Daniel | Canevesi, Rafael L.S. | Morallon, Emilia | Cazorla-Amorós, Diego | Celzard, Alain | Fierro, Vanessa |
Grupo/s de investigación o GITE: | Materiales Carbonosos y Medio Ambiente | Electrocatálisis y Electroquímica de Polímeros |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Materiales |
Palabras clave: | Oxygen reduction reaction | N-doped carbons | Selective functionalization | Textural properties |
Fecha de publicación: | 5-oct-2023 |
Editor: | Elsevier |
Cita bibliográfica: | Journal of Colloid and Interface Science. 2024, 654(Part A): 446-453. https://doi.org/10.1016/j.jcis.2023.10.013 |
Resumen: | Nitrogen-doped carbon-based electrodes are among the most promising alternatives to platinum-based electrodes in the cathode of fuel cells and metal-air batteries, where the oxygen reduction reaction (ORR) takes place. Among the approaches for improving ORR activity, nitrogen functionalities and well-developed textural properties have proved very effective. Nonetheless, the question of which between nitrogen active sites or textural properties are more crucial in N-doped carbon materials remains unanswered. This work proposes a comparative and critical approach through the selective functionalization of four commercial activated carbons with different textural properties. This study highlights the greater importance of N-doping in relation to the textural properties of carbon materials, and provides fundamental insights for conclusively addressing the ongoing debate within the carbon community about the significance of these two factors in the context of ORR. |
Patrocinador/es: | The ANR-15-IDEX-04-LUE project and the TALiSMAN and TALiSMAN2 projects funded by the European Regional Development Fund (ERDF) are gratefully acknowledged. The authors would also like to thank project PID2021-123079OB-I00 funded by MCIN/AEI/10.13039/501100011033 and “ERDF A way of making Europe”. Finally, JQB thanks the Ministerio de Universidades, the European Union, and the University of Alicante for their financial support (MARSALAS21-21). |
URI: | http://hdl.handle.net/10045/137865 |
ISSN: | 0021-9797 (Print) | 1095-7103 (Online) |
DOI: | 10.1016/j.jcis.2023.10.013 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2023 Elsevier Inc. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.jcis.2023.10.013 |
Aparece en las colecciones: | INV - GEPE - Artículos de Revistas INV - MCMA - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Quilez-Bermejo_etal_2023_JColloidInterfaceSci_accepted.pdf | Embargo 24 meses (acceso abierto: 6 oct. 2025) | 3 MB | Adobe PDF | Abrir Solicitar una copia |
Quilez-Bermejo_etal_2023_JColloidInterfaceSci_final.pdf | Versión final (acceso restringido) | 5,85 MB | Adobe PDF | Abrir Solicitar una copia |
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