New recyclable Co-based trimetallic zeolite imidazolate framework (Cu-Ni@ZIF-67) as an efficient catalyst for different reduction reactions
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Título: | New recyclable Co-based trimetallic zeolite imidazolate framework (Cu-Ni@ZIF-67) as an efficient catalyst for different reduction reactions |
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Autor/es: | Naghshbandi, Zhwan | Gholinejad, Mohammad | Sansano, Jose M. |
Grupo/s de investigación o GITE: | Síntesis Asimétrica (SINTAS) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Trimetallic zeolite imidazolate framework | Trimetallic | Catalyst | Reduction |
Fecha de publicación: | 25-jun-2023 |
Editor: | Elsevier |
Cita bibliográfica: | Polyhedron. 2023, 243: 116523. https://doi.org/10.1016/j.poly.2023.116523 |
Resumen: | In recent years, the excellent pore volume, huge specific surface area, and easy functionalizable zeolitic imidazolate frameworks (ZIFs), as new type of porous materials, attracted the attention of scientists. In this work, the new Co-based trimetallic Cu-Ni@ZIF-67 was synthesized using embedded the Cu-Ni precursor in ZIF-67. The structure, morphology and properties of Cu-Ni@ZIF-67 was characterized by the various analysis. The catalytic performance of Cu-Ni@ZIF-67 was investigated for tetracycline (TC) degradation and nitroarenes reduction at room temperature. The resultant catalyst was demonstrated excellent TC degradation efficiency by persulfate (PS) activation in the water during 30 min, and Cu-Ni@ZIF-67 was displayed superior catalytic activity for nitroarenes reduction in the presence of NaBH4. Comparing catalytic activity of Cu-Ni@ZIF-67 with Cu/ZIF-67, Ni/ZIF-67, Cu-Ni and ZIF-67 indicated higher activity of Cu-Ni@ZIF-67. Moreover, the recyclability and stability of this catalyst were surveyed. |
Patrocinador/es: | The authors are grateful to Institute for Advanced Studies in Basic Sciences (IASBS) Research Council and the University of Alicante. We also thankful for financial support to the Iran National Science Foundation (INSF-Grant number of 4003055), Ministerio de Ciencia, Innovación y Universidades (RED2018 -102387 -T, PID201 9-107268GB -100), FEDER, and the Generalitat Valencian a (IDIFEDER/2021/013). |
URI: | http://hdl.handle.net/10045/135707 |
ISSN: | 0277-5387 (Print) | 1873-3719 (Online) |
DOI: | 10.1016/j.poly.2023.116523 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2023 Elsevier Ltd. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.poly.2023.116523 |
Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Naghshbandi_etal_2023_Polyhedron_final.pdf | Versión final (acceso restringido) | 9,19 MB | Adobe PDF | Abrir Solicitar una copia |
Naghshbandi_etal_2023_Polyhedron_revised.pdf | Embargo 24 meses (acceso abierto: 26 jun. 2025) | 2,56 MB | Adobe PDF | Abrir Solicitar una copia |
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