Acidochromism of amino-substituted indolizine chromophores: Towards white light emission
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Título: | Acidochromism of amino-substituted indolizine chromophores: Towards white light emission |
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Autor/es: | Antón-Cánovas, Teresa | Achelle, Sylvain | Fernández-Liencres, M. Paz | Navarro, Amparo | Alonso, Francisco | Rodríguez-López, Julián |
Grupo/s de investigación o GITE: | Nuevos Materiales y Catalizadores (MATCAT) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Indolizines | Photophysical properties | Fluorescence | DFT calculations |
Fecha de publicación: | 2-abr-2023 |
Editor: | Elsevier |
Cita bibliográfica: | Journal of Molecular Liquids. 2023, 380: 121758. https://doi.org/10.1016/j.molliq.2023.121758 |
Resumen: | There is a continuous interest in the development of advanced materials with tunable photophysical properties, among which white light emission represents a major challenge. Indolizines are a kind of azaheterocycles that have gained a great deal of attention in the recent past due to their intriguing photophysical behavior. We report herein on the synthesis of new push–pull indolizines bearing amino and electron-withdrawing groups at positions 1 and 7, respectively, and on their optical response in acidic medium. Exclusive protonation on the amino group has led to a hypsochromic shift in the emission spectra. Interestingly, white photoluminescence can be attained by adjusting the amount of acid as a result of color complementarity between neutral and charged species. Moreover, Density Functional Theory (DFT) calculations on the molecular structure and photophysical properties of these compounds are in agreement with the experimental results, providing very useful information about the main electronic transitions and the influence of protonation on the optical transitions. |
Patrocinador/es: | This work was supported by Spanish Ministerio de Ciencia e Innovación (project CTQ2017-88171-P), Generalitat Valenciana (projects AICO/2017/007 and APOTIP/2021/018), Vicerrectorado de Investigación–Universidad de Alicante (grant UAFPU20-02 for T.A.-C.), Instituto de Síntesis Orgánica (ISO)–Universidad de Alicante, Junta de Comunidades de Castilla-La Mancha/FEDER (project SBPLY/21/180501/000042), Junta de Andalucía (FQM-337), and Universidad de Jaén–FEDER/UJA/2020 (project 2021/00627/001). The Centro de Servicios de Informática y Redes de Comunicaciones (CSIRC, Universidad de Granada) was instrumental in providing the computer time that made this work possible. |
URI: | http://hdl.handle.net/10045/133709 |
ISSN: | 0167-7322 (Print) | 1873-3166 (Online) |
DOI: | 10.1016/j.molliq.2023.121758 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/). |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.molliq.2023.121758 |
Aparece en las colecciones: | INV - MATCAT - Artículos de Revistas |
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Anton-Canovas_etal_2023_JMolecularLiquids.pdf | 2,95 MB | Adobe PDF | Abrir Vista previa | |
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