Zeolitic imidazolate frameworks-67 (ZIF-67) supported PdCu nanoparticles for enhanced catalytic activity in Sonogashira-Hagihara and nitro group reduction under mild conditions
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| Título: | Zeolitic imidazolate frameworks-67 (ZIF-67) supported PdCu nanoparticles for enhanced catalytic activity in Sonogashira-Hagihara and nitro group reduction under mild conditions |
|---|---|
| Autor/es: | Gholinejad, Mohammad | Naghshbandi, Zhwan | Sansano, Jose M. |
| Grupo/s de investigación o GITE: | Síntesis Asimétrica (SINTAS) |
| Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Palabras clave: | ZIF-67 | Palladium | Cobalt | Copper | Sonogashira | Reduction reaction |
| Área/s de conocimiento: | Química Orgánica |
| Fecha de publicación: | 5-ene-2022 |
| Editor: | Elsevier |
| Cita bibliográfica: | Molecular Catalysis. 2022, 518: 112093. https://doi.org/10.1016/j.mcat.2021.112093 |
| Resumen: | A bimetallic PdCu supported on amine functionalized ZIF-67 is shown to be efficient catalyst in Sonogashira-Hagihara coupling reaction of aryl iodides at room temperature and aryl bromides at 40 ºC. In addition, the catalyst is used in the reduction of 4-nitrophenol (4-NP) at room temperature. The analyses of several experiments are developed in order to demonstrate the existence of synergetic affects between Pd, Cu and Co particles in the named reactions. The stability and reusability of this catalyst are also assessed and its efficiency is compared with other reported catalysts in the same transformations. |
| Patrocinador/es: | The authors are grateful to Institute for Advanced Studies in Basic Sciences (IASBS) Research Council and Iran National Science Foundation (INSF-Grant number of 4003055) for support of this work. We are also thankful for financial support to the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013–43446-P and CTQ2014–51912-REDC), the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016–76782-P, CTQ2016–80375-P, CTQ2017–82935-P and PID2019–107268GB-I00), the Generalitat Valenciana (IDIFEDER/2021/013) and the University of Alicante. |
| URI: | http://hdl.handle.net/10045/120614 |
| ISSN: | 2468-8231 |
| DOI: | 10.1016/j.mcat.2021.112093 |
| Idioma: | eng |
| Tipo: | info:eu-repo/semantics/article |
| Derechos: | © 2021 Elsevier B.V. |
| Revisión científica: | si |
| Versión del editor: | https://doi.org/10.1016/j.mcat.2021.112093 |
| Aparece en las colecciones: | INV - SINTAS - Artículos de Revistas |
Archivos en este ítem:
| Archivo | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
 Gholinejad_etal_2022_MolCatal_final.pdf | Versión final (acceso restringido) | 11,94 MB | Adobe PDF | Abrir Solicitar una copia |
 Gholinejad_etal_2022_MolCatal_revised.pdf | Versión revisada (acceso abierto) | 4,41 MB | Adobe PDF | Abrir Vista previa |
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