Synthesis, structure and bioactivity of a mononuclear octahedral [Prolinate2-Na(MeOH)4]−H+ complex

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Title: Synthesis, structure and bioactivity of a mononuclear octahedral [Prolinate2-Na(MeOH)4]−H+ complex
Authors: Belveren, Samet | Poyraz, Samet | Ülger, Mahmut | Pask, Christopher M. | Dondas, H. Ali | Sansano, Jose M.
Research Group/s: Síntesis Asimétrica (SINTAS)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica
Keywords: Prolinate | Sodium complex | Mononuclear | Antimicrobial
Knowledge Area: Química Orgánica
Issue Date: 1-May-2020
Publisher: Elsevier
Citation: Inorganica Chimica Acta. 2020, 504: 119456. doi:10.1016/j.ica.2020.119456
Abstract: The synthesis of a mononuclear octahedral [Prolinate2-Na(MeOH)4]−H+ complex is achieved from a [3 + 2] cycloadduct with excess of NaOMe in methanol. The slow crystallization provides the hexacoordinated complex stabilized by four molecules of solvent. The antibacterial, antifungal and anti-tuberculosis activity of this compound is also evaluated.
Sponsor: This work is a part of Samet Belveren's ongoing PhD thesis granted by Mersin University (Project no. BAP-SBE TEB(SB) 2017-2-TP3-2564). We gratefully acknowledge financial support from Mersin University and the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC), the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016-76782-P and CTQ2016-81797-REDC), the Generalitat Valenciana (PROMETEOII/2014/017), University of Alicante and Mersin University (Project. MEU-2017-COL-01007-M150D).
URI: http://hdl.handle.net/10045/102192
ISSN: 0020-1693 (Print) | 1873-3255 (Online)
DOI: 10.1016/j.ica.2020.119456
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2020 Elsevier B.V.
Peer Review: si
Publisher version: https://doi.org/10.1016/j.ica.2020.119456
Appears in Collections:INV - SINTAS - Artículos de Revistas

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