Transition metal-catalyzed reactions of N-sulfinyl imines
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http://hdl.handle.net/10045/115393
| Title: | Transition metal-catalyzed reactions of N-sulfinyl imines |
|---|---|
| Authors: | Foubelo, Francisco | Nájera, Carmen | Sansano, Jose M. | Yus, Miguel |
| Research Group/s: | Síntesis Asimétrica (SINTAS) |
| Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
| Keywords: | Chiral sulfinyl imines | Transition metals | Addition reactions | Hydrogenations | Transfer hydrogenations |
| Knowledge Area: | Química Orgánica |
| Issue Date: | 8-Jun-2021 |
| Publisher: | Elsevier |
| Citation: | Tetrahedron Letters. 2021, 73: 153104. https://doi.org/10.1016/j.tetlet.2021.153104 |
| Abstract: | Transition metal-catalyzed reactions of N-sulfinyl imines with several substrates lead to the corresponding chiral amines with high yields and diastereo- or enantioselectivities. As metals, titanium, copper, ruthenium, rhodium, palladium and silver have been successfully used as catalysts in different carbon–carbon forming reactions as well as hydrogenations with molecular hydrogen or transfer hydrogenations with isopropanol as hydrogen source. |
| Sponsor: | We thank the continuous financial support from the Spanish Ministerio de Economía y Competitividad (MINECO; project CTQ2016-81797-REDC, CTQ2017-85093-P), Ministerio de Ciencia, Innovación y Universidades (RED2018-102387-T, PID2019-107268 GB-100), FEDER, the Generalitat Valenciana (PROMETEOII/2014/017), and the University of Alicante (VIGROB-068). |
| URI: | http://hdl.handle.net/10045/115393 |
| ISSN: | 0040-4039 (Print) | 1873-3581 (Online) |
| DOI: | 10.1016/j.tetlet.2021.153104 |
| Language: | eng |
| Type: | info:eu-repo/semantics/article |
| Rights: | © 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
| Peer Review: | si |
| Publisher version: | https://doi.org/10.1016/j.tetlet.2021.153104 |
| Appears in Collections: | INV - SINTAS - Artículos de Revistas |
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| File | Description | Size | Format | |
|---|---|---|---|---|
 Foubelo_etal_2021_TetrahedronLett_final.pdf | 840,31 kB | Adobe PDF | Open Preview | |
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