Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene
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Title: | Charge transfer, bonding conditioning and solvation effect in the activation of the oxygen reduction reaction on unclustered graphitic-nitrogen-doped graphene |
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Authors: | Ferre-Vilaplana, Adolfo | Herrero, Enrique |
Research Group/s: | Electroquímica de Superficies |
Center, Department or Service: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Keywords: | Oxygen reduction reaction | Unclustered graphitic-nitrogen-doped graphene | Charge transfer | Bonding conditioning | Solvation effect |
Knowledge Area: | Química Física |
Issue Date: | 26-May-2015 |
Publisher: | Royal Society of Chemistry |
Citation: | Physical Chemistry Chemical Physics. 2015, 17: 16238-16242. doi:10.1039/C5CP00918A |
Abstract: | The monodentate associative chemisorption of molecular oxygen on unclustered graphitic-nitrogen-doped graphene requires two nitrogen dopants per activated molecule. Significant charge transfers from regions corresponding to distant nitrogen-dopants, the presence of a nitrogen-dopant adjacent to the carbon atom acting as an active site, which favours its transition from a sp2 hybridization state to sp3, and the solvation effect turn the investigated mechanism to a favourable process. |
Sponsor: | This work has been financially supported by the MICINN (Spain) (project 2013-44083-P) and Generalitat Valenciana (project PROMETEOII/2014/013). |
URI: | http://hdl.handle.net/10045/52067 |
ISSN: | 1463-9076 (Print) | 1463-9084 (Online) |
DOI: | 10.1039/C5CP00918A |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence |
Peer Review: | si |
Publisher version: | http://dx.doi.org/10.1039/C5CP00918A |
Appears in Collections: | INV - EQSUP - Artículos de Revistas |
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2015_Ferre_Vilaplana_PCCP.pdf | 1,68 MB | Adobe PDF | Open Preview | |
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