On the origin of the high capacitance of nitrogen-containing carbon nanotubes in acidic and alkaline electrolytes
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Title: | On the origin of the high capacitance of nitrogen-containing carbon nanotubes in acidic and alkaline electrolytes |
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Authors: | Ornelas, Omar | Sieben, Juan Manuel | Ruiz-Rosas, Ramiro | Morallon, Emilia | Cazorla-Amorós, Diego | Geng, Junfeng | Soin, Navneet | Siores, Elias | Johnson, Brian F.G. |
Research Group/s: | Electrocatálisis y Electroquímica de Polímeros | Materiales Carbonosos y Medio Ambiente |
Center, Department or Service: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Keywords: | Synthesis | Nitrogenated carbon nanotubes | High capacitance | Acidic and alkaline electrolytes |
Knowledge Area: | Química Física | Química Inorgánica |
Issue Date: | 31-Jul-2014 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications. 2014, 50: 11343-11346. doi:10.1039/C4CC04876H |
Abstract: | The synthesis of nitrogenated carbon nanotubes (N-CNTs) with up to 6.1 wt% N, via the use of pyridine as the nitrogen containing carbon precursor, can provide a facile route to significantly enhance the low intrinsic specific capacitance of carbon nanotubes. The nitrogen functionalities determine this, at least, five-fold increase of the specific capacitance. |
Sponsor: | This work was supported by the Ministry of Economy and competitiveness of Spain (MINECO) and FEDER (MAT2010-15273, MAT2013-42007-P, CTQ2012/31762) and Generalitat Valenciana (PROMETEO/2013/038 and PROMETEOII/2014/010). OOD thanks the Generalitat Valenciana for his Grisolia grant. RRR thanks MINECO for ‘Juan de la Cierva’ contract (JCI-2012-12664). |
URI: | http://hdl.handle.net/10045/44754 |
ISSN: | 1359-7345 (Print) | 1364-548X (Online) |
DOI: | 10.1039/C4CC04876H |
Language: | eng |
Type: | info:eu-repo/semantics/article |
Rights: | © Royal Society of Chemistry 2014 |
Peer Review: | si |
Publisher version: | http://dx.doi.org/10.1039/C4CC04876H |
Appears in Collections: | INV - GEPE - Artículos de Revistas INV - MCMA - Artículos de Revistas |
Files in This Item:
File | Description | Size | Format | |
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2014_Ornelas_etal_ChemComm_final.pdf | Versión final (acceso restringido) | 1,84 MB | Adobe PDF | Open Request a copy |
2014_Ornelas_etal_ChemComm_rev.pdf | Versión revisada (acceso abierto) | 1,29 MB | Adobe PDF | Open Preview |
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