Albaladejo-Fuentes, Vicente, Sánchez-Adsuar, María Salvadora, Anderson, James A., Illán-Gómez, María José
NOx Storage on BaTi0.8Cu0.2O3 Perovskite Catalysts: Addressing a Feasible Mechanism
Albaladejo-Fuentes V, Sánchez-Adsuar M-S, Anderson JA, Illán-Gómez M-J. NOx Storage on BaTi0.8Cu0.2O3 Perovskite Catalysts: Addressing a Feasible Mechanism. Nanomaterials. 2021; 11(8):2133. https://doi.org/10.3390/nano11082133
URI: http://hdl.handle.net/10045/117305
DOI: 10.3390/nano11082133
ISSN: 2079-4991
Abstract: 
The NOx storage mechanism on BaTi0.8Cu0.2O3 catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage–regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba2TiO4 plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O2 and NO/N2 show that nitrites and nitrates are formed on the perovskite during the NOx storage process. Thus, it seems that, as for model NSR catalysts, the NOx storage on BaTi0.8Cu0.2O3 catalyst takes place by both “nitrite” and “nitrate” routes, with the main pathway being highly dependent on the temperature and the time on stream: (i) at T < 350 °C, NO adsorption leads to nitrites formation on the catalyst and (ii) at T > 350 °C, the catalyst activity for NO oxidation promotes NO2 generation and the nitrate formation.
Keywords:NOx storage mechanism, In situ DRIFTS, Nitrites, Nitrates, Barium-titanium perovskite
MDPI
info:eu-repo/semantics/article