Carbon‐Bridged p‐Phenylenevinylene Polymer for High‐Performance Solution‐Processed Distributed Feedback Lasers

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Title: Carbon‐Bridged p‐Phenylenevinylene Polymer for High‐Performance Solution‐Processed Distributed Feedback Lasers
Authors: Morales Vidal, Marta | Quintana Arévalo, José Antonio | Villalvilla Soria, José Moisés | Boj Giménez, Pedro | Nishioka, Hiroki | Tsuji, Hayato | Nakamura, Eiichi | Whitworth, Guy L. | Turnbull, Graham A. | Samuel, Ifor D.W. | Díaz-García, María A.
Research Group/s: Física de la Materia Condensada
Center, Department or Service: Universidad de Alicante. Departamento de Física Aplicada | Universidad de Alicante. Departamento de Óptica, Farmacología y Anatomía | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Conjugated polymers | Distributed feedback lasers | Oligomer | Organic semiconductors
Knowledge Area: Física Aplicada | Óptica | Física de la Materia Condensada
Issue Date: 4-Jul-2018
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA
Citation: Advanced Optical Materials. 2018, 6(13): 1800069. doi:10.1002/adom.201800069
Abstract: Thin‐film organic lasers are attractive light sources for a variety of applications. Recently, it is reported that carbon‐bridged oligo(p‐phenylenevinylene)s (COPVn with repeating unit n = 1–6) function as unique laser dyes which combine high fluorescence efficiency, wavelength tunability, and both thermal and photostability, making them ideal for use in organic semiconductor lasers. However, in order to obtain such excellent properties, COPVn require blending in a matrix, such as a thermoplastic polymer, thus leading to miscibility issues, limited absorption, and charge transporting properties. Here, high‐performance lasers with a novel active polymer poly‐COPV1, based on the basic unit of COPV1 and prepared as a high‐quality neat film, are reported which overcome the trade‐off between the device performance and durability. The prepared lasers show thresholds 30 times lower and operational lifetimes 300 times longer than devices based on COPV1 dispersed in polystyrene. The low threshold operation allows the poly‐COPV1 lasers to be pumped by a nitride diode laser.
Sponsor: The Spanish team acknowledges support from the Spanish Government (MINECO) and the European Community (FEDER) through Grant Nos. MAT2011-28167-C02-01 and MAT2015-66586-R. M.M-V. was partly supported by a MINECO FPI Fellowship (No. BES-2009-020747) and by a Junta de Castilla y León (JCYL) Postdoctoral Fellowship (No. SA046U16). The Japanese authors thank the financial support from MEXT (16H04106 for H.T. and 15H05754 for E.N.). The St Andrews team acknowledge support from the Engineering and Physical Sciences Research Council through grants EP/K503162/1 and EP/J009016/1. I.D.W.S. acknowledges a Royal Society Wolfson Research Merit Award.
URI: http://hdl.handle.net/10045/77335
ISSN: 2195-1071
DOI: 10.1002/adom.201800069
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Peer Review: si
Publisher version: https://doi.org/10.1002/adom.201800069
Appears in Collections:INV - Física de la Materia Condensada - Artículos de Revistas
INV - GHPO - Artículos de Revistas

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