Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes

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Title: Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes
Authors: Alonso, Diego A. | Baeza, Alejandro | Chinchilla, Rafael | Gómez Lucas, Cecilia | Guillena, Gabriela | Pastor, Isidro M. | Ramón, Diego J.
Research Group/s: Catálisis Estereoselectiva en Síntesis Orgánica (CESO) | Nuevos Materiales y Catalizadores (MATCAT)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica
Keywords: Nitroalkenes | Michael addition | Organocatalysis | Asymmetric synthesis
Knowledge Area: Química Orgánica
Issue Date: 29-May-2017
Publisher: MDPI
Citation: Alonso DA, Baeza A, Chinchilla R, Gómez C, Guillena G, Pastor IM, Ramón DJ. Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes. Molecules. 2017; 22(6):895. doi:10.3390/molecules22060895
Abstract: The asymmetric conjugate addition of carbon and heteroatom nucleophiles to nitroalkenes is a very interesting tool for the construction of highly functionalized synthetic building blocks. Thanks to the rapid development of asymmetric organocatalysis, significant progress has been made during the last years in achieving efficiently this process, concerning chiral organocatalysts, substrates and reaction conditions. This review surveys the advances in asymmetric organocatalytic conjugate addition reactions to α,β-unsaturated nitroalkenes developed between 2013 and early 2017.
Sponsor: We thank the financial support from the Spanish Ministerio de Economía, Industria y Competitividad (CTQ2015-66624-P) and the University of Alicante (UAUSTI16-03, AUSTI16-10, VIGROB-173, VIGROB-285).
URI: http://hdl.handle.net/10045/66372
ISSN: 1420-3049
DOI: 10.3390/molecules22060895
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2017 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
Peer Review: si
Publisher version: http://dx.doi.org/10.3390/molecules22060895
Appears in Collections:INV - CESO - Artículos de Revistas
INV - MATCAT - Artículos de Revistas
INV - AMIC - Artículos de Revistas

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