Organocatalyzed Assembly of Chlorinated Quaternary Stereogenic Centers

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dc.contributorCatálisis Estereoselectiva en Síntesis Orgánica (CESO)es_ES
dc.contributorNuevos Materiales y Catalizadores (MATCAT)es_ES
dc.contributor.authorGómez-Martínez, Melania-
dc.contributor.authorAlonso, Diego A.-
dc.contributor.authorPastor, Isidro M.-
dc.contributor.authorGuillena, Gabriela-
dc.contributor.authorBaeza, Alejandro-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Orgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Síntesis Orgánicaes_ES
dc.identifier.citationAsian Journal of Organic Chemistry. 2016, 5(12): 1428-1437. doi:10.1002/ajoc.201600404es_ES
dc.identifier.issn2193-5807 (Print)-
dc.identifier.issn2193-5815 (Online)-
dc.description.abstractThe catalytic asymmetric construction of chiral quaternary stereocenters is a continual area of research for organic chemists. In this sense, when a chlorine atom is introduced to a quaternary stereocenter, the synthetic difficulty of the resulting molecule increases along with its significance. This is true not only because of the intrinsic interest in such chlorinated molecules but also because they are highly valuable chiral building blocks in organic synthesis, as they can be converted into more complex molecules by a SN2 displacement reaction. Among the different strategies to create chlorinated quaternary stereogenic centers, organocatalysis has played a pivotal role over the past decade. In this review, a comprehensive analysis of such organocatalyzed transformations with a focus on the α-chlorination of carbonyl compounds is presented.es_ES
dc.description.sponsorshipFinancial support from the University of Alicante (VIGROB-173) and the Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) is acknowledged.es_ES
dc.publisherWiley-VCH Verlag GmbH & Co. KGaAes_ES
dc.rights© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimes_ES
dc.subjectAsymmetric catalysises_ES
dc.subjectCarbonyl compoundses_ES
dc.subjectQuaternary stereocenterses_ES
dc.subject.otherQuímica Orgánicaes_ES
dc.titleOrganocatalyzed Assembly of Chlorinated Quaternary Stereogenic Centerses_ES
Appears in Collections:INV - CESO - Artículos de Revistas
INV - MATCAT - Artículos de Revistas
INV - AMIC - Artículos de Revistas

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