The chemical and electrochemical oxidative polymerization of 2-amino-4-tert-butylphenol

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Title: The chemical and electrochemical oxidative polymerization of 2-amino-4-tert-butylphenol
Authors: Abidi, Mohamed | López-Bernabeu, Sara | Huerta Arráez, Francisco | Montilla, Francisco | Besbes-Hentati, Salma | Morallon, Emilia
Research Group/s: Electrocatálisis y Electroquímica de Polímeros
Center, Department or Service: Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Electrochemical polymerization | In situ FTIR | Polyaminophenol
Knowledge Area: Química Física
Issue Date: 10-Sep-2016
Publisher: Elsevier
Citation: Electrochimica Acta. 2016, 212: 958-965. doi:10.1016/j.electacta.2016.07.060
Abstract: Poly(2-amino-4-tert-butylphenol), poly(2A-4TBP), was synthesized from monomer aqueous solution using either electrochemical or chemical oxidation procedures. Several spectroscopic characterization techniques were employed to gain information on the chemical structure and redox behavior of the obtained materials. It was found that the chemical polymerization product could be described as an oligomer mixture containing up to 16 monomer units. In parallel to other polymers derived from o-aminophenol, phenoxazine rings constitute also the basic structure of poly(2A-4TBP). In addition, the occurrence of N-N couplings, which are favored by the presence of the voluminous tert-butyl substituent, seems also relevant. No significant structural differences were found between the chemically or electrochemically synthesized materials.
Sponsor: Financial support from the Spanish Ministerio de Economía y Competitividad and FEDER funds (MAT2013-42007-P) and from the Generalitat Valenciana (PROMETEO2013/038) is gratefully acknowledged. M. Abidi thanks the Ministry of Higher Education and Scientific Research of Tunisia for funding her stay at the University of Alicante.
URI: http://hdl.handle.net/10045/57683
ISSN: 0013-4686 (Print) | 1873-3859 (Online)
DOI: 10.1016/j.electacta.2016.07.060
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2016 Published by Elsevier Ltd.
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.electacta.2016.07.060
Appears in Collections:INV - GEPE - Artículos de Revistas

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