Metal and metalloid determination in biodiesel and bioethanol

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Title: Metal and metalloid determination in biodiesel and bioethanol
Authors: Sánchez, Raquel | Sánchez, Carlos | Lienemann, Charles Philippe | Todolí Torró, José Luis
Research Group/s: Análisis de Polímeros y Nanomateriales
Center, Department or Service: Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología
Keywords: Metal | Metalloid | Biodiesel | Bioethanol
Knowledge Area: Química Analítica
Issue Date: 2015
Publisher: Royal Society of Chemistry
Citation: Journal of Analytical Atomic Spectrometry. 2015, 30: 64-101. doi:10.1039/C4JA00202D
Abstract: Biofuel quality control involves the determination of metal and metalloid content. These species play a very important role because they may modify the efficiency of biofuel production as well as the stability of these products. Furthermore, some metals are toxic and generate environmental concerns whereas others are used as additives. Normally, products such as biodiesel and bioethanol are mixed with conventional fossil fuels (diesel and gasoline, respectively). Therefore, metals come from the raw product employed for biofuel production (seeds, sugars…) as well as from the production and storage process or even from the added fuels. The determination of the final metal and metalloid concentration in biofuels is a challenging subject because of several reasons. On the one hand, their content is usually low (i.e., from several μg L−1 to mg L−1) and, hence, sensitive techniques should be used. Besides all these, calibration with organic complex matrices becomes more difficult and degrades the accuracy of the determination. Several approaches have been evaluated to carry out this kind of analysis going from spectrochemical to electroanalytical techniques. Within the first group, Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Mass Spectrometry (ICP-MS) are often employed together with atomic absorption methods. The different procedures applied will be discussed in the present review emphasizing the most widely employed ones. On this subject, fundamental as well as applied studies related to the biofuel analysis through ICP-OES and ICP-MS will be shown to illustrate the current difficulties associated with these determinations. Comments regarding the possible solutions proposed to overcome the drawbacks encountered will be made.
URI: http://hdl.handle.net/10045/52809
ISSN: 0267-9477 (Print) | 1364-5544 (Online)
DOI: 10.1039/C4JA00202D
Language: eng
Type: info:eu-repo/semantics/article
Rights: © Royal Society of Chemistry 2015
Peer Review: si
Publisher version: http://dx.doi.org/10.1039/C4JA00202D
Appears in Collections:INV - NANOBIOPOL - Artículos de Revistas
INV - bioCir - Artículos de Revistas
INV - bioCir - Artículos de Revistas

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