Surface-Sensitive Electrooxidation of Carbon Monoxide in Room Temperature Ionic Liquids

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Title: Surface-Sensitive Electrooxidation of Carbon Monoxide in Room Temperature Ionic Liquids
Authors: Hanc-Scherer, Florin A. | Sánchez-Sánchez, Carlos M. | Ilea, Petru | Herrero, Enrique
Research Group/s: Electroquímica de Superficies
Center, Department or Service: Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica
Keywords: CO oxidation | Ionic liquids | Structure sensitive catalysis | Platinum electrodes | Crystallographic planes
Knowledge Area: Química Física
Issue Date: 8-Nov-2013
Publisher: American Chemical Society
Citation: ACS Catalysis. 2013, 3(12): 2935-2938. doi:10.1021/cs4007364
Abstract: Electrooxidation of CO at the Pt(hkl)-electrolyte interface in two different room temperature ionic liquids (RTILs) is probed to be surface-sensitive. Provided data reveal a specific surface structure, (110) sites, which selectively activate CO oxidation in RTILs. This new knowledge is crucial for designing the next generation of Pt nanosized electrocatalysts for the CO oxidation reaction by increasing that type of site on the catalyst surface.
Sponsor: Florin A. Hanc-Scherer and Petru Ilea gratefully acknowledge the support of the Sectorial Operational Programme for Human Resources Development 2007-2013, cofinanced by the European Social Fund under the Project POSDRU/107/1.5/S/76841.
ISSN: 2155-5435
DOI: 10.1021/cs4007364
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2013 American Chemical Society
Peer Review: si
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Appears in Collections:INV - EQSUP - Artículos de Revistas

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