Alcohols as electrophiles in C-C bond-forming reactions: the hydrogen autotransfer process

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Title: Alcohols as electrophiles in C-C bond-forming reactions: the hydrogen autotransfer process
Authors: Guillena, Gabriela | Ramón, Diego J. | Yus, Miguel
Research Group/s: Derivados de Aminoácidos y Péptidos en Síntesis Orgánica
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica
Keywords: Alcohols | Alkylation | C-C coupling | Hydrogen transfer | Synthetic methods
Knowledge Area: Química Orgánica
Issue Date: 25-Jan-2007
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Citation: GUILLENA TOWNLEY, Gabriela; RAMÓN DANGLA, Diego José; YUS ASTIZ, Miguel. "Alcohols as electrophiles in C-C bond-forming reactions: the hydrogen autotransfer process". Angewandte Chemie International Edition. Vol. 46, Issue 14 (2007). ISSN 1433-7851, pp. 2358-2364
Abstract: The hydrogen autotransfer process involves an initial oxidative hydrogen elimination, followed by different types of reactions, and is completed with a reductive hydrogen addition to give the final product. The sequence allows the alkylation of different nucleophilic agents using environmentally benign alcohols as electrophiles, mild conditions, and soft bases, with water produced as the only waste material. Recent examples of modulating the organometallic catalyst have also lent themselves to expansion of the range of available substrates, as described in this Minireview.
URI: http://hdl.handle.net/10045/2686
ISSN: 1433-7851
DOI: 10.1002/anie.200603794
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1002/anie.200603794
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