Asymmetric aldol reaction with BINAM-sulfonyl polymeric organocatalyst
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http://hdl.handle.net/10045/25968
| Title: | Asymmetric aldol reaction with BINAM-sulfonyl polymeric organocatalyst |
|---|---|
| Authors: | Bañón Caballero, Abraham | Guillena, Gabriela | Nájera, Carmen |
| Research Group/s: | Derivados de Aminoácidos y Péptidos en Síntesis Orgánica | Procesos Catalíticos en Síntesis Orgánica |
| Center, Department or Service: | Universidad de Alicante. Departamento de Química Orgánica |
| Keywords: | Asymmmetic | Aldol | Polymer | Organocatalyst |
| Knowledge Area: | Química Orgánica |
| Issue Date: | 17-Dec-2012 |
| Publisher: | Georg Thieme Verlag |
| Citation: | BAÑÓN-CABALLERO, A.; GUILLENA, G.; NÁJERA, C. “Asymmetric aldol reaction with BINAM-sulfonyl polymeric organocatalyst”. Synfacts. Vol. 9, No. 1 (2013). ISSN 1861-1958, p. 114 |
| Abstract: | The BINAM-sulfonyl polymeric organocatalysts was prepared by the AIBN-promoted copolymerization of BINAM-derived sulfonamide, styrene and divinylbenzebe. The polymer catalyzed the asymmetric aldol reaction of aliphatic ketones with aromatic aldehydes to give the aldol products in up to 83% yield and with up to 95% ee. The catalysts could be recovered upt to 6 times with only a slight decrease on its activity. |
| URI: | http://hdl.handle.net/10045/25968 |
| ISSN: | 1861-1958 (Print) | 1861-194X (Online) |
| DOI: | 10.1055/s-0032-1317913 |
| Language: | eng |
| Type: | info:eu-repo/semantics/review |
| Rights: | © Georg Thieme Verlag Stuttgart · New York |
| Peer Review: | si |
| Publisher version: | http://dx.doi.org/10.1055/s-0032-1317913 |
| Appears in Collections: | INV - PCSO - Artículos de Revistas INV - DAPSO - Artículos INV - SINTAS - Artículos de Revistas INV - CESO - Artículos de Revistas |
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| File | Description | Size | Format | |
|---|---|---|---|---|
 rp-Y14112sf-2.pdf | Versión final (acceso restringido) | 142,29 kB | Adobe PDF | Open Request a copy |
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