Photoelectrocatalytic production of solar fuels with semiconductor oxides: materials, activity and modeling
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Título: | Photoelectrocatalytic production of solar fuels with semiconductor oxides: materials, activity and modeling |
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Autor/es: | Monllor-Satoca, Damián | Díez García, María Isabel | Lana-Villarreal, Teresa | Gómez, Roberto |
Grupo/s de investigación o GITE: | Grupo de Fotoquímica y Electroquímica de Semiconductores (GFES) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Palabras clave: | Photoelectrocatalytic production | Solar fuels | Semiconductor oxides |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | 9-sep-2020 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | Chemical Communications. 2020, 56: 12272-12289. https://doi.org/10.1039/D0CC04387G |
Resumen: | Oxide photoelectrochemistry has been under continuous development over the last half century. These decades have witnessed the use of electrodes of different nature (from single crystals to nanoparticulate films), new electrode materials (including ternary and multinary transition metal oxides), and different strategies for improving their efficiency and stability (e.g. doping or protective layers). Although the very high initial expectations for using oxide electrodes in solar energy conversion were not fully met, substantial efforts have been devoted to reach an in-depth understanding of the processes limiting their functioning, providing firm bases for further developments. In this article, we review our main contributions in this field; in particular, we focus on the water photooxidation (i.e. oxygen evolution reaction), water photoreduction (i.e. hydrogen evolution reaction) and full water splitting processes (in a tandem cell) with binary and ternary oxides, including metal hydroxides as co-catalysts. We emphasize the importance of modeling and obtaining mechanistic insights and we conclude with a reflection on the main issues to be tackled in this field, which in our opinion should experience major advances in the coming years. |
Patrocinador/es: | Continued support from the Spanish Ministry of Science and Innovation (MICINN) is gratefully acknowledged, in particular through the current project RTI2018-102061-B-I00 (FONDOS FEDER). Financial support from the Generalitat Valenciana through project PROMETEO/2020/089 is also thanked. |
URI: | http://hdl.handle.net/10045/109844 |
ISSN: | 1359-7345 (Print) | 1364-548X (Online) |
DOI: | 10.1039/D0CC04387G |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © The Royal Society of Chemistry 2020 |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1039/D0CC04387G |
Aparece en las colecciones: | INV - GFES - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Monllor-Satoca_etal_2020_ChemCommun_final.pdf | Versión final (acceso restringido) | 5,57 MB | Adobe PDF | Abrir Solicitar una copia |
Monllor-Satoca_etal_2020_ChemCommun_accepted.pdf | Accepted Manuscript (acceso abierto) | 3,04 MB | Adobe PDF | Abrir Vista previa |
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