Deep eutectic solvents: cutting-edge applications in cross-coupling reactions
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Título: | Deep eutectic solvents: cutting-edge applications in cross-coupling reactions |
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Autor/es: | Hooshmand, Seyyed Emad | Afshari, Ronak | Ramón, Diego J. | Varma, Rajender S. |
Grupo/s de investigación o GITE: | Alternative Methodologies In Chemistry (AMIC) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Deep eutectic solvents | Cross-coupling reactions | Transition metals | Carbon–carbon bond formation | Green solvents |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 21-may-2020 |
Editor: | Royal Society of Chemistry |
Cita bibliográfica: | Green Chemistry. 2020, 22: 3668-3692. doi:10.1039/D0GC01494J |
Resumen: | Deep eutectic solvents (DESs), surmised as “the organic reaction medium of the century”, have reverberated a new symphony throughout the present green millennium. A brief historical account of the DES systems and their physicochemical properties as task-specific and designer solvents for cross-coupling reactions are appraised including the hole theory that explains the underlying mechanistic pathway for this emerging neoteric medium. The insights into cross-coupling reactions and their applications are included, highlighting the significant achievements pertaining to the dual role of DESs as a solvent and catalyst. In addition, popular “name-reactions” for the carbon–carbon and carbon–heteroatom bond formations related to the nature of DESs and the core optimum conditions are included. The review also encompasses the novel approaches to privileged catalytic systems and identify the voids left in cross-coupling reactions where DES systems have not made inroads yet. Finally, the challenges of utilizing the neoteric derivatives of DES for these reactions are expounded. |
Patrocinador/es: | S. E. H. and R. A. are grateful to the Iran Science Elites Federation (ISEF). D. J. R. gratefully acknowledges financial support from the Spanish Ministerio de Economía, Industria y Competitividad (PGC2018-096616-B-100) and University of Alicante (VIGROB-316FI). |
URI: | http://hdl.handle.net/10045/107885 |
ISSN: | 1463-9262 (Print) | 1463-9270 (Online) |
DOI: | 10.1039/D0GC01494J |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © The Royal Society of Chemistry 2020 |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1039/D0GC01494J |
Aparece en las colecciones: | INV - AMIC - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Hooshmand_etal_2020_GreenChem_final.pdf | Versión final (acceso restringido) | 3,51 MB | Adobe PDF | Abrir Solicitar una copia |
Hooshmand_etal_2020_GreenChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 1,53 MB | Adobe PDF | Abrir Vista previa |
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