Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds

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Title: Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds
Authors: Bosque, Irene | Chinchilla, Rafael | Gonzalez-Gomez, Jose C. | Guijarro, David | Alonso, Francisco
Research Group/s: Nuevos Materiales y Catalizadores (MATCAT) | Catálisis Estereoselectiva en Síntesis Orgánica (CESO)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica
Keywords: Cross-dehydrogenative coupling | Benzylation | Allylation | C–H bonds
Knowledge Area: Química Orgánica
Issue Date: 26-May-2020
Publisher: Royal Society of Chemistry
Citation: Organic Chemistry Frontiers. 2020, 7: 1717-1742. doi:10.1039/d0qo00587h
Abstract: In recent years, the cross-dehydrogenative coupling (CDC) has demonstrated to be a powerful synthetic tool to form C–C bonds from two C–H bonds. This high atom-economic transformation is an attractive alternative to the classical substitution and coupling approaches for the benzylation and allylation of carbon centers, which rely on the reaction of adequately functionalized starting materials. This review emphasizes the utility of the CDC through the coupling of benzylic and allylic C–H bonds with C(sp)–H, C(sp2)–H and C(sp3)–H bonds.
Sponsor: This work was generously supported by the Spanish Ministerio de Ciencia, Innovación y Universidades (MICIU; grant no. CTQ2017-88171-P), the Generalitat Valenciana (GV; grant no. AICO/2017/007) and the Universidad de Alicante (grant no. VIGROB-285/19). I. B. is also grateful to the Spanish MICIU for a Juan de la Cierva-incorporación grant (no. IJCI-2017-33706).
URI: http://hdl.handle.net/10045/107847
ISSN: 2052-4110 (Print) | 2052-4129 (Online)
DOI: 10.1039/d0qo00587h
Language: eng
Type: info:eu-repo/semantics/article
Rights: © the Partner Organisations 2020
Peer Review: si
Publisher version: https://doi.org/10.1039/d0qo00587h
Appears in Collections:INV - MATCAT - Artículos de Revistas
INV - CESO - Artículos de Revistas

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