González García, José, Gallud Martínez, Francisco, Iniesta, Jesus, Montiel, Vicente, Aldaz Riera, Antonio, Lasia, Andrzej
Kinetics of electrocrystallization of PbO2 on glassy carbon electrodes: partial inhibition of the progressive three-dimensional nucleation and growth
GONZÁLEZ GARCÍA, José, et al. "Kinetics of electrocrystallization of PbO2 on glassy carbon electrodes: partial inhibition of the progressive three-dimensional nucleation and growth". Journal of the Electrochemical Society. Vol. 147, Issue 8 (Aug. 2000). ISSN 0013-4651, pp. 2969-2974
URI: http://hdl.handle.net/10045/8480
DOI: 10.1149/1.1393633
ISSN: 0013-4651
Abstract: 
Electrocrystallization of PbO2 on glassy carbon electrodes was studied in 1 M HNO3 + 0.1 M Pb(NO3)2 using cyclic voltammetry rotating disk electrode experiments, chronoamperometry, and scanning electron microscopy. In order to explain the experimental curves, a new theory of three-dimensional nucleation and progressive growth was developed and applied to analyze the experimental chronoamperometric curves. Numerical approximations led to the determination of kinetic parameters.
Keywords:Electrodeposition, Nucleation, Charge transfer, Lead dioxide
The Electrochemical Society
info:eu-repo/semantics/article