TY - JOUR TI - Solubility, Density, Refractive Index, and Viscosity for the Polyhydric Alcohol + CsBr + H2O Ternary Systems at Different Temperatures AU - Li, Yanjie AU - Li, Shu’ni AU - Zhai, Quanguo AU - Marcilla, Antonio AU - Jiang, Yucheng AU - Hu, Mancheng DA - 2013-05-10 UR - http://hdl.handle.net/10045/40349 AB - The solubility, density, refractive index, and viscosity data for the ethylene glycol + CsBr + H2O, 1,2-propanediol + CsBr + H2O, and glycerin + CsBr + H2O ternary systems have been determined at (288.15, 298.15, and 308.15) K. In all cases, the solubility of CsBr in aqueous solutions was decreased significantly due to the presence of polyhydric alcohol. The liquid–solid equilibrium experimental data were correlated using the NRTL (nonrandom two-liquid) activity coefficient model, considering nondissociation of the dissolved salt in the liquid phase, and new interaction parameters were estimated. The mean deviations between calculated and experimental compositions were low, showing the good descriptive quality and applicability of the NRTL model. The refractive indices, densities, and viscosities for the unsaturated solutions of the three ternary systems have also been measured at three temperatures. Values for all of the properties were correlated with the salt concentrations and proportions of polyhydric alcohol in the solutions. KW - Solubility KW - Density KW - Refractive index KW - Viscosity KW - Polyhydric alcohol + CsBr + H2O ternary systems DO - 10.1021/je301222e SN - 0021-9568 (Print) PB - American Chemical Society ER -