Starch functionalized creatine for stabilization of gold nanoparticles: Efficient heterogeneous catalyst for the reduction of nitroarenes
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http://hdl.handle.net/10045/93790
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DC Field | Value | Language |
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dc.contributor | Síntesis Asimétrica (SINTAS) | es_ES |
dc.contributor.author | Gholinejad, Mohammad | - |
dc.contributor.author | Dasvarz, Neda | - |
dc.contributor.author | Shojafar, Mohammad | - |
dc.contributor.author | Sansano, Jose M. | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Orgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica | es_ES |
dc.date.accessioned | 2019-07-04T10:25:56Z | - |
dc.date.available | 2019-07-04T10:25:56Z | - |
dc.date.issued | 2019-09-01 | - |
dc.identifier.citation | Inorganica Chimica Acta. 2019, 495: 118965. doi:10.1016/j.ica.2019.118965 | es_ES |
dc.identifier.issn | 0020-1693 (Print) | - |
dc.identifier.issn | 1873-3255 (Online) | - |
dc.identifier.uri | http://hdl.handle.net/10045/93790 | - |
dc.description.abstract | Selective reduction of nitroaromatic pollutants into amines with recoverable and reusable heterogeneous catalysts is highly desirable. Herein, we prepared and characterized an efficient novel catalyst comprising 4 nm size Au nanoparticles supported on creatine modified starch. Using this catalyst, efficient reduction of nitroarenes into amines at room temperature in aqueous media was achieved. The presence of creatine in the structure of the catalyst plays important role in amount of Au loading, efficiency of the catalyst, recycling times, and leaching of Au compared to starch supported Au without creatine. | es_ES |
dc.description.sponsorship | The authors are grateful to Institute for Advanced Studies in Basic Sciences (IASBS) Research Council and Iran National Science Foundation (INSF-Grant number of 97021804) for support of this work. We also gratefully acknowledge financial support from the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC), the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER, EU) (projects CTQ2016-76782-P and CTQ2016-81797-REDC), the Generalitat Valenciana (PROMETEOII/2014/017) and the University of Alicante. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.rights | © 2019 Elsevier B.V. | es_ES |
dc.subject | Starch | es_ES |
dc.subject | Creatine | es_ES |
dc.subject | Gold | es_ES |
dc.subject | Nitro | es_ES |
dc.subject | Reduction | es_ES |
dc.subject | Heterogeneous | es_ES |
dc.subject.other | Química Orgánica | es_ES |
dc.title | Starch functionalized creatine for stabilization of gold nanoparticles: Efficient heterogeneous catalyst for the reduction of nitroarenes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1016/j.ica.2019.118965 | - |
dc.relation.publisherversion | https://doi.org/10.1016/j.ica.2019.118965 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
Appears in Collections: | INV - SINTAS - Artículos de Revistas |
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File | Description | Size | Format | |
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2019_Gholinejad_etal_InorganicaChimicaActa_final.pdf | Versión final (acceso restringido) | 2,71 MB | Adobe PDF | Open Request a copy |
2019_Gholinejad_etal_InorganicaChimicaActa_accepted.pdf | Accepted Manuscript (acceso abierto) | 2,45 MB | Adobe PDF | Open Preview |
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